Time lapse chemical fertilizer monitoring in agriculture sandy soil

Geoelectrical resistivity, hydrogeochemical and soil properties analysis methods were used for chemical fertilizer monitoring in sandy soil at a palm oil plantation in Machang, Malaysia. The time lapse monitoring was done using these methods five times within a three-month period. The hydrogeochemical analysis was conducted over three auger holes to a depth of 1 meter and sampled at 25 centimeter intervals. Chemical fertilizer was applied to the 21 x 21 square meter area after the first data set measurement. Areas outside of this fertilized zone are considered a non-fertilized zone. The other four data sets were acquired at about equal time intervals, thus giving a four-post fertilization data set. The hydrogeochemical measurements indicate that the cations content are relatively similar for every time lapse measurement. However, relatively higher changes of anions content occur at the surface level to a depth of 1 meter. Of particular interest is the nitrate concentration above the limit for safe human consumption as it returns to the initial value about 100 days after fertilization. The geoelectrical model prior to fertilization showed similar resistivity values at near surface to a depth of about 75 centimetres with no significant occurrences of low resistivity values. Lower resistivity values were obtained during the second, third, fourth and fifth measurements within the chemically fertilized zone. In the last measurement, the resistivity values in the fertilized zone are almost similar to the non-fertilized zone. This indicates that the contaminant has dissolved into the surrounding environment within this time period

Heavy metals accumulation in plants growing in ex tin mining catchment

The degree of contamination by heavy metals [arsenic, copper, lead, tin and zinc] in soil and transfer to plants has been studied. Specimens of plant species from five locations in an area of 10 x 10 m were sampled with their corresponding soils. Thirty six plant species including two shallow water aquatic plants were identified. Soil and plant specimens were analyzed by using inductively coupled plasma optical emission spectrometry. It was found that metal concentration in soil was highly variable while concentration of metals in plants directly depends on the concentration of metals it was rooted. Roots showed highest metal concentration followed by leaves, shoots and flowers. Bioconcentraion factor and translocation factor were calculated, representing Cyperus rotundus L. as a potential tin-hyperaccumulator plant, previously not reported in literature. Plant Species Imperata cylindrica, Lycopodium cernuum, Melastoma malabathricum, Mimosa pudica Linn, Nelumbo nucifera, Phragmites australis L., Pteris vittata L. and Salvinia molesta, were metal accumulator while Acacia podalyriaefolia G. Don, Bulb Vanisium, Dillenia reticulate King, Eugenia reinwardtiana, Evodia roxburghiania Hk. f. clarke, Gleichenia linearis, Grewia erythrocarpa Ridl., Manihot esculenta Crantz, Paspalum conjugatum Berguis, Passiflora suberosa, Saccharum officinarum, Stenochlaena palustris [Burm.] Bedd. and Vitis trifolia Linn. were tolerated plant species. All other studied plants were excluders. Identified plant species could be useful for revegetation and erosion control in metals contaminated ex-mining sites. Morphological changes such as reduction in size, change in color and deshaping have also been observed in plant species with high metal values

Study of mango biomass [Mangifera indica L] as a cationic biosorbent

Unfertilizable fruiting buds of mango plant Mangifera indica L, an agrowaste, is used as a biomass in this study. The efficacy of the biosorbent was tested for the removal of lead, copper, zinc and nickel metal ions using batch experiments in single and binary metal solution under controlled experimental conditions. It is found that metal sorption increases when the equilibrium metal concentration rises. At highest experimental solution concentration used [150 mg/L], the removal of metal ions were 82.76% for lead, 76.60% for copper, 63.35% for zinc and 59.35% for nickel while at lowest experimental solution concentration [25 mg/L], the removal of metal ions were 92.00% for lead, 86.84% for copper, 83.96% for zinc and 82.29% for nickel. Biosorption equilibrium isotherms were plotted for metal uptake capacity [q] against residual metal concentrations [C f] in solution. The q versus [C f]sorption isotherm relationship was mathematically expressed by Langmuir and Freundlich models. The values of separation factor were between zero and one indicating favourable sorption for four tested metals on the biosorbent. The surface coverage values were approaching unity with increasing solution concentration indicating effectiveness of biosorbent under investigation. The non-living biomass of Mangifera indica L present comparable biosorption capacity for lead, copper, zinc and nickel metal ions with other types of biosorbent materials found in literature and is effective to remove metal ions from single metal solutions as well as in the presence of other co-ions with the main metal of solution