1.
Lebanese Science Journal. 2003; 4 (1): 107-120
in English
| IMEMR
| ID: emr-63307
ABSTRACT
Vibrationally excited Nitrosyl Chloride and Nitric Oxide NO [X2pi, v" = 10] have been observed in absorption, following incoherent UV [lamda = 340 nm] photo dissociation of ClNO-inert gas mixtures. The paper reports studies on the spectroscopic and kinetic properties of these two species and present evidence for near-resonance vibrational energy transfer from nascent NO [X2pi, v" = 10] into the v1 vibrational mode of ClNO and from vibrationally excited Cl2 formed in the reaction of Cl atoms with ClNO into the v2of ClNO