ABSTRACT
The sorption of cadmium and humic acids from aqueous solutions using surface-modified nanozeolite A has been investigated under various examination conditions. The morphology of untreated and treated nanozeolite was studied under scanning electron microscope and transmission electron microscope. Isotherms of cadmium adsorption onto surface-modified nanozeolite A were studied at different pH, solid to liquid ratio, adsorbate concentration and interaction time. Kinetic and equilibrium studies were conducted and the equilibrium data have been analyzed using Langmuir and Freundlich isotherm models. The study revealed that experimental results were in agreement with the Freundlich model. The Langmuir monolayer adsorption capacity was found to be 1666.67 g cadmium and 6.75 g humic acid per gram of modified nanozeolite A, which is higher than that of reported value for other zeolites. The sorption ability was enhanced by surface modification and reduction in size and enabled the zeolite to adsorb cadmium. The adsorption of cadmium and humic acid on nanozeolite was found to be the highest at pH 6 and 3, respectively. Results showed that solid to liquid ratio and pH are the most important factors for cadmium and humic acid removal, respectively. Effect of competitive ions was studied and results showed that there is no competition between cadmium and humic acid sorption and presence of these ions
Subject(s)
Humic Substances , Adsorption , SolutionsABSTRACT
Drinking water quality after treatment and before reaching the consumer could be affected by distribution pipes, service lines and Home devices. The structure of water coolers, a home device that are widely used in warm months of the year, could potentially affect the quality of drinking water. The aim of this study was to assess the microbial and chemical quality of water from conventional water coolers. Water samples were collected from 29 water cooler systems at the Isfahan university of medical sciences. 29 control samples also obtained from the nearest drinking water taps. All samples were examined for total heterotrophic bacteria and physicochemical parameters including temperature, ph, turbidity and heavy metals. All samples from the water cooler systems complied with the EPA guidelines for total heterotrophic bacteria count. There were no significant differences between the levels of heavy metals in water samples from the water cooler systems and taps. There was only a significant difference between the level of Cu in the water samples from cooler systems and taps The overall results of this study indicated that the use of water cooler systems from hygienic point of view could not cause any problems for consumers