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1.
J Environ Biol ; 2007 Oct; 28(4): 765-9
Article Dans Anglais | IMSEAR | ID: sea-113794

Résumé

Husk of tur dal (Cajanus cajan) was investigated as a new biosorbent for the removal of Fe (III) and Cr (VI) ions from aqueous solutions. Parameters like agitation time, adsorbent dosage and pH were studied at different initial Fe (III) and Cr (VI) concentrations. The biosorptive capacity of the Tur dal husk was dependent on the pH of the chromium and iron solution, with pH 2 and 2.5 respectively being optimal. The adsorption data fit well with Langmuir and Freundlich isotherm models. The practical limiting adsorption capacity (qmax) calculated from the Langmuir isotherm was 96.05 mg of Cr(VI)/ g of the biosorbent at an initial pH of 2.0 and 66.65 mg/g at pH 2.5. The infrared spectra of the biomass revealed that hydroxyl, carboxyl and amide bonds are involved in the uptake of Cr (VI) and Fe (III) ions. Characterisation of tur dal husk has revealed that it is an excellent material for treating wastewaters containing low concentration of metal ions.


Sujets)
Adsorption , Cajanus/composition chimique , Chrome/isolement et purification , Composés du fer III/isolement et purification
2.
Electron. j. biotechnol ; 8(3)Dec. 2005. graf, tab
Article Dans Anglais | LILACS | ID: lil-448798

Résumé

The potential to remove Cr (VI) from aqueous solutions through biosorption using the husk of Bengal gram (Cicer arientinum), was investigated in batch experiments. The results showed removal of 99.9 percent of chromium in the 10 mgl-1 chromium solution, the biomass required at saturation was 1 g mg-1. Kinetic experiments revealed that the dilute chromium solutions reached equilibrium within 180 min. The biosorptive capacity of the (bgh) was dependent on the pH of the chromium solution, with pH 2 being optimal. The adsorption data fit well with the Langmuir and Freundlich isotherm models. The adsorption capacity calculated from the Langmuir isotherm was 91.64 mg Cr (VI)/g at pH 2. The adsorption capacity increased with increase in agitation speed and an optimum was achieved at 120 rpm. The biosorption of Cr (VI) was studied by Fourier transform infrared spectroscopy (FTIR), which suggested that the presence of Cr (VI) ions in the biomass affects the bands corresponding to hydroxyl and carboxyl groups. Comprehensive characterisation of parameters indicates bgh to be an excellent material for biosorption of Cr (VI) to treat wastewaters containing low concentration of the metal.


Sujets)
Cicer/métabolisme , Chrome/métabolisme , Purification de l'eau/méthodes , Adsorption , Agriculture , Dépollution biologique de l'environnement , Biomasse , Cicer/composition chimique , Chrome/composition chimique , Spectroscopie infrarouge à transformée de Fourier , Concentration en ions d'hydrogène , Déchets industriels , Cinétique , Solutions , Température
3.
J Biosci ; 1994 Mar; 19(1): 75-80
Article Dans Anglais | IMSEAR | ID: sea-160898

Résumé

Rana tigrina and Tomopterna breviceps occur as sympatric species at Dharwad, India. Sexually mature males produce advertisement calls. The advertisement call of both the species consist of a number of calls produced in series forming a call group· Each call group of Rana tigrina comprises 10-40 calls, whereas that of Tomopterna breviceps consists 13-141 calls. Each call consists of a pulse group with variable number of pulses which lack pulse interval. Calls of both the species exhibit similarities in (i) call consisting of series of calls with a pulse group in each call, (ii) absence of pulse interval within the pulse group, (iii) the amplitude of the first pulse being always small, and (iv) the frequency spectrum beginning from 200 Hz. Based on the similarities in the spectral features of the calls, it is suggested that the two species may be closely related to each other.

4.
J Biosci ; 1993 June; 18(2): 239-245
Article Dans Anglais | IMSEAR | ID: sea-160908

Résumé

The period of calling activity of Polypedates maculatus lies between April and October. Males possess an indistinct subgular vocal sac which turns yellow during the breeding season. Mating calls type I, type II and distress calls have been identified. Mating calls type I and type II consist of a single pulse group. Type I call comprises of 7-22 pulses, whereas type II call consists of 4-6 pulses. Pulses are short. The frequency spectrum is broad and continuous. Distress calls, with 6 hormonics, are given by the females with their mouth open.

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