Influence of bioactive particles and onium salt on the physicochemical properties of experimental infiltrants

Abstract This study evaluated physicochemical properties of experimental infiltrants after addition of hydroxyapatite nanoparticles (HAp) or 58S bioactive glass (BAG) and diphenyliodonium hexafluorophosphate (DPI). The resin matrix was composed of TEGDMA/Bis-EMA (3:1), 0.5 mol% CQ, and 1 mol% EDAB. The blends received or not 0.5 mol% DPI and 10% wt BAG or HAp. Icon was used as commercial control. The groups were characterized by XRD, FT-IR spectrometry, and SEM before and after simulated body fluid (SBF) immersion for up to 7 days. Polymerization kinetics (n =3 ), water sorption and solubility (n=10), and viscosity (n = 3) were surveyed. For polymerization kinetics, the samples were polymerized for 5 min and the data were obtained from 40 s and 5 min. Statistical analysis was made using ANOVA and Tukey's test (a = 0.05). After 7 days of SBF immersion, XRD and FT-IR showed that the HAp crystalline phase was present only in the HAp groups. A lower degree of conversion (DC) and polymerization rate were observed for the Icon and BAG groups, whereas HAp showed higher values. For the BAG group, DPI increased polymerization rate and DC in 40 s. After 5 min, all groups presented DC above 80%. In groups with particles, the HAp groups exhibited higher viscosity, whereas DPI groups showed a decrease in viscosity. Icon had the highest water sorption. To conclude, BAG neither improved the physicochemical properties studied, nor did it show bioactive properties. The addition of DPI reduced viscosity caused by particle addition and also attenuated the DC decrease caused by BAG addition. The addition of bioactive particles to infiltrants should be seen with caution because they increase viscosity and may not bring major clinical improvements that justify their use. DPI might be indicated only if any component is added to the infiltrant to act as a compensation mechanism.

Thiourethane-functionalized fillers: biological properties and degradation resistance

Abstract This study determined the effect of thiourethane-functionalized fillers (TU) on the antimicrobial properties, cytotoxicity, degree of conversion (DC), water sorption (Wsp) and solubility (Wsl) of experimental composites. TU-modified fillers were added at different ratios in experimental composites: 0 (Control-TU0), 25% (TU25), 50% (TU50), 75% (TU75) and 100wt% (TU100). The antimicrobial properties were detected through the exhaustion test and counting of Streptococus mutans colonies for biofilm formation. Cytotoxicity to human gingival fibroblasts was evaluated in three different parameters: XTT (2,3-Bis-(2-Methoxy-4-Nitro-5-Sulfophenyl)-2H-Tetrazolium-5-Carboxanilide), NRU (Neutral Red Uptake assay) and CVDE (Crystal Violet Dye Exclusion test)) at the same cells. ELISA was used to measure the IL-6 and b-FGF biomarkers. DC was determined by Fourier-transformed infrared spectroscopy, while Wsp and Wsl by mass variations. Inhibitory capacity of biofilm formation was not observed for any material. All groups presented at least 70% of cell survival within the observed periods (24h and 7 days). Positive control (toxic) had high IL-6 values and low b-FGF values. No significant variations in DC, Wsp, and Wsl were observed among the experimental groups. The use of thiourethane did not present antimicrobial and cytotoxic activity and the tested materials presented equivalent properties to those conventionally used in dentistry.

Strategies for potential toughening of acrylic denture bases polymerized with microwave energy

Abstract Thiourethane additives have been shown to improve properties in several dental polymer applications. The aim of this study was to verify the effect of the addition of thiourethane oligomers and acrylamide or isobornyl-based plasticizers on the physical properties of the denture base acrylic resin polymerized with microwaves. Thiourethane oligomer (TU) was synthetized and added to microwaved acrylic resin in proportions varying between 3 and 14 wt%. Separate experimental groups included the addition of dimethyl acrylamide (DMAM) and isobornyl methacrylate as plasticizers, at concentrations varying from 5 to 20 wt%. Samples were polymerized using microwave energy at 500 Watts for 3 min, deflasked at room temperature, stored in water at 37 °C for 24 h, and evaluated for: linear dimensional change, gloss, Knoop hardness, surface roughness, impact strength, yield strength, elastic modulus, toughness, yield strength, viscosity, glass transition temperature and network heterogeneity, and water sorption/solubility. Data were analyzed with ANOVA/Tukey's post-hoc test (a=5%). The addition of TU led to properties that were similar or worse than the materials to which it was not added, except for dimensional stability. The impact on properties was statistically significant for all materials above 20% addition of TU. The addition of DMAM at 5 wt% or isobornyl methacrylate at 10 wt% improved yield strength and modulus, but increased water sorption and solubility. Except for dimensional stability, the addition of thiourethane oligomers to acrylic denture base materials compromised most tested properties. The use of DMAM and isobornyl methacrylate improved properties for selected compositions.

Resumo Aditivos de tiouretano demonstraram melhorar propriedades de polímeros em diversas aplicações. O objetivo deste estudo foi verificar o efeito da adição de oligômeros de tiouretano, monômeros de acrilamida ou baseados em funcionalidade isobornil na propriedades físicas de bases de dentadura de acrílico polimerizadas em micro-ondas. O oligômero de tiouretano (TU) foi sintetizado e adicionado à resina acrílica em proporções variando de 3 a 14% em peso. Dimetil acrilamida (DMAM) e isobornil metacrilato (IBMA) foram adicionados em formulações separadas como plastificantes em concentrações variando de 5 a 20% em peso. As amostras foram polimerizadas usando energia de micro-ondas (500 Watts oor 3 min), desincluídas da mufla a temperature ambiente, armazenadas em água a 37°C por 24 h, e submetidas aos testes de: alteração dimensional linear, brilho, dureza Knoop, rugosidade superficial, resistência ao impacto, tensão normal de escoamento, módulo de elasticidade, tenacidade, viscosidade, temperatura de transição vítrea e heterogeneidade da rede polimérica, além de sorção de água e solubilidade. Os dados foram analisados com ANOVA e teste de Tukey (a=5%). A adição de TU não afetou ou diminuiu todas as propriedades, exceto pela estabilidade dimensional. O impacto nas propriedades foi estatisticamente significante para todos os materiais em concentrações acima de 20% de TU. Isso pode ser explicado por um encurtamento das cadeias e diminuição do empacotamento das cadeias lineares do PMMA. A adição de 5% de DMAM ou 10% de isobornil metacrilato melhoraram a tensão de escoamento e o módulo, mas aumentaram a sorção de água e solubilidade. Exceto pela estabilidade dimensional, a adição de oligômeros de tiouretano à bases de dentatura compostas por resina acrílica prejudicou todas a propriedades testadas. O uso de DMAM e isobornil metacrilato melhorou as propriedades para composições selecionadas.

Can composition and preheating improve infiltrant characteristics and penetrability in demineralized enamel?

Abstract The composition of infiltrants can influence their physical properties, viscosity and depth of penetration (DP). Strategies are used to increase the DP, such as the addition of diluents or the use of heat. This study aimed to evaluate the effect of preheating and composition on physical properties and DP of infiltrants in demineralized enamel. The groups were assigned, and the following experimental formulations were made: 25%BisEMA +75%TEGDMA; 25%BisEMA +65%TEGDMA +10%ethanol; 25%BisEMA +65%TEGDMA +10%HEMA; 100%TEGDMA; 90%TEGDMA +10%ethanol; 90%TEGDMA +10%HEMA. The samples were photoactivated at two temperatures (25°C and 55°C). Degree of conversion (DC) was performed using an infrared spectrophotometer. Elastic modulus (E), flexural strength (FS) and contact angle (CA) tests were also performed. The DP of an infiltrant in demineralized enamel was determined by confocal laser scanning microscopy (CLSM) using an indirect labeling technique. The data were analyzed by two-way ANOVA and Tukey's test. DC increased after preheating in all the groups; however, 90%TEGDMA+10%ethanol showed the lowest DC for both temperatures, and the lowest E. Preheating did not influence E or FS. The CA increased at 55°C for most groups, but decreased for groups containing HEMA. Temperature did not seem to influence DP, and Icon showed the lowest DP values. The 100%TEGDMA composition showed more homogeneous penetration, whereas Icon showed heterogeneous and superficial penetration. The preheating technique does not improve all properties in all the material compositions. The composition of a material can influence and improve its properties.

Characterization of residual stresses in veneering ceramics for prostheses with zirconia framework

Abstract The aim of this study was to evaluate the influence of the coefficient of thermal expansion (CTE or α) and glass transition temperature (Tg) of three veneering ceramics used with zirconia frameworks of full-arch fixed prostheses. The generation of residual stresses and linear contraction after the simulation of the cooling process and mechanical loading were measured. The analysis was based on the finite element method in three-dimensional model of a maxillary full-arch fixed prosthesis with zirconia framework (e.max ZirCAD) and veneer by felsdpathic ceramics (GEC - IPS e.max Ceram, GVM - Vita VM9 and GLC - Lava Ceram). The linear contraction simulation was performed by cooling the structures from the Tg of each veneer ceramic at room temperature (25°C). A loading of 100 N on the occlusal region of the first molar was performed. The magnitude of the maximum principal stress (smax) and linear contraction were evaluated. The levels of CTE mismatch between veneering ceramics and framework showed no relevant influence on smax and linear contraction. The Tg values of the veneer ceramic showed to be directly proportional to amount of smax and linear contraction. The GEC presented the highest values of smax and linear contraction. The GVM and GLC did not present significant differences between them. In conclusion, GVM was similar to GLC, while GEC presented differences in relation to other veneer ceramics in terms of residual stress and linear contraction.

Resumo O objetivo neste estudo foi avaliar a influência do coeficiente de expansão térmica (CET) e da temperatura de transição vítrea (Tg) de três cerâmicas feldspáticas utilizadas para o recobrimento da infraestrutura de zircônia em prótese total fixa. A tensão residual e contração linear após a simulação do processo de esfriamento e carga oclusal foram mensuradas. A análise foi efetuada pelo método por elementos finitos num modelo tridimensional de uma prótese total maxilar com infraestrutura em zircônia (e.max ZirCAD) recoberta por três cerâmicas felsdpáticas (GEC - IPS e.max Ceram, GVM - Vita VM9 ou GLC - Lava Ceram). A simulação da contração linear foi realizada pelo esfriamento da estrutura a partir da Tg de cada cerâmica de cobertura até a temperatura ambiente (25 °C). Em seguida, um carregamento de 100 N foi realizado na região oclusal de primeiro molar. A magnitude da tensão máxima principal (smax) e contração linear foram avaliadas. Os níveis de diferença de CTE entre cerâmica de cobertura e infraestrutura não apresentaram influência significante na smax e na contração linear. Os valores da Tg da cerâmica de cobertura foram diretamente proporcionais à quantidade de smax e contração linear. O grupo GEC apresentou os maiores valores de smax e contração linear, enquanto os grupos GVM e GLC com menores valores não apresentaram diferenças significantes entre si. Em conclusão, o grupo GVM foi similar ao GLC, enquanto o grupo GEC apresentou diferenças em relação a outras cerâmicas de cobertura quanto à tensão residual e contração linear.

Implant inclination and horizontal misfit in metallic bar framework of overdentures: analysis by 3d-fea method

Abstract The aim of this study was to evaluate by three-dimensional finite element analysis (3D-FEA) the biomechanics involved in bar-framework system for overdentures. The studied factors were latero-lateral angulation in the right implant (-10, -5, 0, 5 and 10 degrees), and different bar cross-sections (circular, Hader and oval) presenting horizontal misfits (50 or 150 µm) on the opposite implant. Positive angulation (5 and 10 degrees) for implant inclination to mesial position, negative angulation (-5 and -10 degrees) for distal position, and zero degree for parallel implants. The von Mises stresses evaluated the bar, screw and the implant; maximum principal, minimum principal and shear stress analyses evaluated the peri-implant bone tissue. Parallel implants provide lower stress in alveolar bone tissue; mesial inclined bars showed the most negative effect on prosthetic structures and implants. In conclusion, bar cross-section showed no influence on stress distribution for peri-implant bone tissue, and circular bar provided better behavior to the prosthetic system. Higher stress concentration is provided to all system as the misfit increases.

Resumo O objetivo neste estudo foi avaliar por meio do método por elemento finito tridimensional (3D-AEF) a biomecânica envolvida na infraestrutura do sistema barra-clipe para overdentures. Os fatores de estudo foram inclinação mésio-distal entre implantes (-10, -5, 0, 5, 10 graus) e diferentes seções transversais da barra metálica (circular, oval e Hader) com desajuste horizontal (50 e 150 µm). Valores de inclinação positivas (5 e 10 graus) indicam inclinação do implante para mesial e valores negativos (-5 e -10 graus) mostram inclinação para distal, enquanto zero grau indica implantes paralelos. Valores de tensões equivalentes de von Mises foram utilizadas nos sistemas barra, parafuso e implante. Tensão máxima e mínima principal, e cisalhante foram utilizadas para análise do osso alveolar peri-implante. Implantes paralelos promoveram menores tensões em tecido peri-implante; as inclinações para mesial apresentaram piores resultados para as estruturas protéticas e implantes. As diferentes seções transversais da barra não mostraram influência na distribuição de tensões no osso alveolar peri-implante. Concluindo, a barra circular apresentou melhores resultados para os componentes protéticos e maiores valores de tensões foram observados em todos os modelos na medida que o desajuste aumentou.

The effect of hydrofluoric acid and resin cement formulation on the bond strength to lithium disilicate ceramic

Abstract To investigate how the hydrofluoric acid (HF) concentrations applied to a lithium disilicate glass-ceramic (EMX) affects the surface morphology and microtensile bond strength (μTBS) of ceramics to dentin, using light-cured resin cements with or without UDMA. Sixty-three EMX square ceramic blocks were etched for 20 seconds using different HF concentrations (1%, 5% and 10%) and luted to dentin using two types of resin cement combinations: BisGMA/TEGDMA and BisGMA/TEGDMA/UDMA (n = 10). Each bonded EMX-dentin block was sectioned to obtain 1 mm2 sticks for μTBS evaluation. Half of the sticks were tested after 24 hours and the other half was assessed after 6 months of water storage. Data were statistically assessed using split-plot three-way ANOVA and multiple comparisons were performed using the Tukey's post hoc test (α = 0.05). One EMX sample from each HF concentration was analyzed using field-emission scanning electron microscope (FE-SEM) to characterize the etching pattern. According to the FE-SEM images, increasing the concentration of HF from 1 to 5 and then to 10% led to increased removal of glassy matrix and greater exposure of lithium disilicate crystals. The 10% HF concentration yielded higher μTBS when compared to 1% for BisGMA/TEGDMA formulation (p < 0.05); whereas HF 1% and 5% showed similar μTBS values when compared to 10% HF for BisGMA/TEGDMA/UDMA resin matrix (p > 0.05) at both storage times. Water aging decreased the μTBS values (p < 0.05), except when 10% HF was associated with BisGMA/TEGDMA resin cement. Resin cement formulation and hydrofluoric acid concentrations can interfere with the immediate and long-term glass-ceramic bond strength to dentin.

Impact of Material Shade and Distance from Light Curing Unit Tip on the Depth of Polymerization of Composites

Abstract This study aimed to evaluate the effect of the composite shade and distance from the light-curing unit (LCU) tip on the irradiance reaching the bottom of composite disks and on the depth of polymerization. Composites of three shades (opaque - OXDC, bleach - BXL, and A2) were inserted into molds with 3-mm of thickness positioned over a spectrometer and photo-activated with the LCU (Bluephase) tip placed at 0 or 1 cm from the composite surface. The mean irradiance reaching the bottom of composite was recorded during the entire photo-activation (30 s). Specimens (2 x 2 x 4 mm) were polymerized and used to map the degree of conversion achieved in different depths from irradiated surface. Specimens were sectioned into slices that were positioned over the platform of the infra-red microscope connected to the spectrometer to map the conversion. The conversion was measured in eight different depths every 500-µm. Increasing the distance of LCU tip reduced the irradiance only for A2. Interposing OXDC disks resulted in lowest values of irradiance and A2 the highest one. A tendency to decrease the conversion was observed towards the bottom of specimens for all experimental conditions, and the slope was more accentuated for OXDC. Differences among shades and distances from LCU tip were evident only beyond 1.5-2.0 mm of depth. In conclusion, both composite shade and distance from LCU tip might affect the light-transmission and depth of polymerization, while the effect of last was more pronounced.

Resumo Este estudo objetivou avaliar o efeito da cor do compósito e da distância da ponta do aparelho fotopolimerizador (AFP) na irradiância alcançando a base do disco de compósito e na profundidade de polimerização. Compósitos de três cores (opaca - OXDC, clareado - BXL, e A2) foram inseridos em moldes com 3 mm de espessura posicionados sobre um espectrômetro e fotoativados com a ponta do AFP (Bluephase) colocada a 0 ou 1 cm da superfície do compósito. A irradiância média alcançando a base do compósito foi registrada durante toda a fotoativação (30 s). Amostras (2 x 2 x 4 mm) de compósito polimerizado também foram confeccionadas e usada para mapear o grau de conversão obtido em diferentes profundidades da superfície irradiada. As amostras foram seccionadas em fatias que foram posicionadas sobre a plataforma de um microscópio infra-vermelho conectado ao espectrômetro para mapear a conversão. A conversão foi mensurada em oito diferentes profundidades com 500-µm entre elas. Aumentando a distância da ponta do AFP reduziu a irradiância apenas para A2. Interpondo discos de OXDC resultou em menores valores de irradiância e A2 nos maiores. Uma tendência de redução na conversão foi observada em direção a base das amostras para todas as condições experimentais, com uma redução mais acentuada para OXDC. Diferenças entre as cores e distâncias da ponta do AFP foram evidentes apenas a partir de 1,2-2,0 mm de profundidade. Como conclusão, tanto a cor do compósito como a distância da ponta do AFP podem afetar a transmissão de luz e a profundidade de polimerização, enquanto que o efeito do último foi mais pronunciado.

Polymerization shrinkage stress of composite resins and resin cements - What do we need to know?

Abstract Polymerization shrinkage stress of resin-based materials have been related to several unwanted clinical consequences, such as enamel crack propagation, cusp deflection, marginal and internal gaps, and decreased bond strength. Despite the absence of strong evidence relating polymerization shrinkage to secondary caries or fracture of posterior teeth, shrinkage stress has been associated with post-operative sensitivity and marginal stain. The latter is often erroneously used as a criterion for replacement of composite restorations. Therefore, an indirect correlation can emerge between shrinkage stress and the longevity of composite restorations or resin-bonded ceramic restorations. The relationship between shrinkage and stress can be best studied in laboratory experiments and a combination of various methodologies. The objective of this review article is to discuss the concept and consequences of polymerization shrinkage and shrinkage stress of composite resins and resin cements. Literature relating to polymerization shrinkage and shrinkage stress generation, research methodologies, and contributing factors are selected and reviewed. Clinical techniques that could reduce shrinkage stress and new developments on low-shrink dental materials are also discussed.

Influence of Photoinitiator System on Physical-Chemical Properties of Experimental Self-Adhesive Composites

Abstract The aim of this study was to determine the influence of photoinitiator systems on physical-chemical properties of flowable composites. Conventional (CFC), composed by bisphenol-glycidyl dimethacrylate (BisGMA)+triethyleneglycol dimethacrylate (TEGDMA), and self-adhesive (SAFC), composed by BisGMA+TEDGMA+bis{2-(methacryloyloxy) ethyl} phosphate (2MP), flowable composites were developed. Five photoinitiator systems were tested: camphorquinone (CQ), ethyl-4-dimethylaminobenzoate (EDMAB), diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO), phenylbis (2,4,6-trimethylbenzoyl)phosphine oxide (BAPO), CQ+EDMAB+TPO and CQ+EDMAB+BAPO. A two-peak LED was used; degree of conversion (DC) and the maximum polymerization rate (RPmax) were determined by near infrared spectroscopy. For the yellowing degree a spectrophotometer was used. Water sorption (Wsp) was obtained after 30 days of water storage (n=5). Data were submitted to two-way analysis of variance and Tukey’s test (a=0.05). BAPO presented the highest DC and RPmax values for both series. SAFCs presented lower DC and RPmax for CQ+EDMAB-based materials. Greater yellowing was observed for SAFCs compared with CFCs, except for BAPO. Greater Wsp was observed for SAFCs compared with CFCs. The photoinitiator did not influence Wsp for CFCs, but TPO and BAPO presented the highest Wsp in SAFCs. The photoinitiator system affected differently the physical-chemical properties of CFCs and SAFCs.

Resumo O objetivo do estudo foi determinar a influência do sistema fotoiniciador sobre as propriedades físico-químicas de compósitos fluidos. Os compósitos convencionais foram compostos por bisfenol-glicidil dimetacrilato (BisGMA) + trietilenoglicol dimetacrilato (TEGDMA), e os autoadesivos, apresentavam BisGMA +TEGDMA+ Bis2(metacriloiloxi)etil fosfato (2 MP). Cinco sistemas fotoiniciadores foram testados: canforquinona + etil-4- dimetilamino benzoato (CQ+EDMAB), óxido mono-alquil fosfínico (TPO) e óxido bis-alquil fosfínico (BAPO), CQ+EDMAB+TPO e CQ+EDMAB+BAPO. LED de amplo espectro foi usado; o grau de conversão (GC) e a taxa de polimerização (TP) foram determinados por espectroscopia próximo ao infravermelho; o grau de amarelo foi mensurado por um espectrofotômetro e absorção de água foi obtida após 30 dias de armazenamento em água (n=5). Os dados foram submetidos a análise de variância de dois fatores e teste de Tukey (?=0,05). BAPO apresentou os maiores valores de GC e TP nos compósitos convencionais e autoadesivos. Compósitos autoadesivos apresentaram menor GC e TP quando CQ+EDMAB foi usado. Maior amarelecimento foi observado nos compósitos autoadesivos em relação aos convencionais, exceto para BAPO. Compósitos autoadesivos promoveram maior absorção de água. Não houve influência dos fotoiniciadores nos compósitos convencionais, no entanto TPO e BAPO apresentaram os maiores valores de absorção de água nos compósitos autoadesivos. Os sistemas fotoiniciadores influenciaram de maneira diferente as propriedades físico-químicas dos compósitos convencionais e autoadesivos.

The Effect of Hydrofluoric Acid Concentration and Heat on the Bonding to Lithium Disilicate Glass Ceramic

Abstract The aim of this study was to evaluate the effects of hydrofluoric acid (HF) concentration and previous heat treatment (PHT) on the surface morphology and micro-shear bond strength (mSBS) of a lithium disilicate glass ceramic (EMX) to resin cement. One hundred four EMX specimens were randomly assigned to two groups (n=52) according to the HF concentration: 5% and 10%. A new random distribution was made according to the PHTs (n=13): control (no PHT); previously heated HF (70 °C); previously heated EMX surface (85 °C); the combination of heated HF + heated EMX surface. The etching time was set at 20 s. All EMX blocks were silanated and received a thin layer of an unfilled resin. Five resin cement cylinders were made on each EMX surface using Tygon tubes as matrices, and then stored for 24 h at 37 °C. One random etched EMX sample from each group was analyzed using field-emission scanning electron microscopy (FE-SEM). The data were subjected to two-way ANOVA and multiple comparisons were performed using the Tukey post hoc test (a=0.05). For the control groups, 5% HF showed statistically lower mSBS values when compared to 10% HF (p<0.05). PHT increased the mSBS values for 5% HF, yielding statistically similar results to non-PHT 10% HF (p<0.05). FE-SEM images showed increased glassy matrix removal when PHT was applied to HF 5%, but not to the same degree as for 10% HF. PHT has the potential to improve the bond strength of 5% HF concentration on lithium disilicate glass ceramic.

Resumo O objetivo deste estudo foi avaliar os efeitos das concentrações de ácido fluorídrico (AF) e do prévio tratamento térmico (PTT) na morfologia da superfície e resistência de união ao microcisalhamento (mRUM) de uma cerâmica vítrea de dissilicato de lítio (EMX) ao cimento resinoso. Cento e quatro espécimes de EMX foram aleatoriamente distribuídos em dois grupos (n=52) de acordo com a concentração do AF: 5% e 10%. Os espécimes foram novamente distribuídos de forma aleatória de acordo com o PTT (n=13): controle (sem PTT); AF previamente aquecido (70 °C); superfície do EMX previamente aquecida (85 °C); combinação entre AF e EMX aquecidos. O tempo de condicionamento foi fixado em 20 s. Todos os espécimes de EMX foram silanizados e receberam a aplicação de uma fina camada de um adesivo sem carga. Cinco cilindros de cimento resinoso foram confeccionados usando tubos Tygon como matrizes e então armazenados por 24 h a 37 °C. Uma amostra condicionada de cada grupo foi aleatoriamente selecionada e analisada em um microscópio eletrônico de varredura em emissão de campo (MEVEC). Os dados foram submetidos ao teste ANOVA de dois fatores e múltiplas comparações foram feitas pelo teste de Tukey (a=0.05). Para os grupos controle, AF 5% mostrou valor de mRUM estatisticamente menor do que AF 10% (p<0.05). PTT aumentou os valores de mRUM para o AF 5%, proporcionando resultados estatisticamente similares ao grupo AF 10% controle (p<0.05). MEVEC mostrou um aumento na remoção da matriz vítrea quando o PTT foi aplicado ao grupo AF 5%, no entanto esse efeito não foi visto no grupo AF 10%. O PTT tem o potencial de melhorar a resistência de união do AF 5% na cerâmica vítrea reforçada por disilicato de lítio.

Repair Strength in Simulated Restorations of Methacrylate- or Silorane-Based Composite Resins

Abstract The study verified the bond strength in simulated dental restorations of silorane- or methacrylate-based composites repaired with methacrylate-based composite. Methacrylate- (P60) or silorane-based (P90) composites were used associated with adhesive (Adper Single Bond 2). Twenty-four hemi-hourglass-shaped samples were repaired with each composite (n=12). Samples were divided according to groups: G1= P60 + Adper Single Bond 2+ P60; G2= P60 + Adper Single Bond 2 + P60 + thermocycling; G3= P90 + Adper Single Bond 2 + P60; and G4= P90 + Adper Single Bond 2 + P60 + thermocycling. G1 and G3 were submitted to tensile test 24 h after repair procedure, and G2 and G4 after submitted to 5,000 thermocycles at 5 and 55 ?#61616;C for 30 s in each bath. Tensile bond strength test was accomplished in an universal testing machine at crosshead speed of 0.5 mm/min. Data (MPa) were analyzed by two-way ANOVA and Tukey's test (5%). Sample failure pattern (adhesive, cohesive in resin or mixed) was evaluated by stereomicroscope at 30?#61655; and images were obtained in SEM. Bond strength values of methacrylate-based composite samples repaired with methacrylate-based composite (G1 and G2) were greater than for silorane-based samples (G3 and G4). Thermocycling decreased the bond strength values for both composites. All groups showed predominance of adhesive failures and no cohesive failure in composite resin was observed. In conclusion, higher bond strength values were observed in methacrylate-based resin samples and greater percentage of adhesive failures in silorane-based resin samples, both composites repaired with methacrylate-based resin.

Resumo O objetivo neste estudo foi verificar a resistência de união em restaurações simuladas de compósitos baseados em metacrilato ou silorano reparadas com compósito à base de metacrilato. Compósitos baseados em metacrilato (Filtek P60; 3M ESPE) ou silorano (Filtek P90; 3M ESPE) foram associados com adesivo (Adper Single Bond 2; 3M ESPE). Vinte e quatro amostras em forma de semi-ampulhetas foram reparadas com cada material (n=12), conforme os grupos experimentais: G1- P60 + Adper Single Bond 2 + P60; G2- P60 + Adper Single Bond 2 + P60 + termociclagem; G3- P90 + Adper Single Bond 2 + P60; e G4- P90 + Adper Single Bond 2 + P60 + termociclagem. Os grupos G1 e G3 foram submetidos ao ensaio de tração após 24 horas do procedimento de reparo e os grupos G2 e G4 depois de submetidos a 5.000 ciclos térmicos de 5 e 55 ?#61616;C por 30 s em cada banho. O teste de resistência à tração foi efetuado em máquina universal atuando numa velocidade de 0,5 mm/min. Os dados (MPa) foram submetidos a ANOVA a dois fatores e teste de Tukey (5%). O padrão de fratura das amostras (adesivo, coesivo em resina ou misto) foi avaliado em estereomicroscópio com aumento de 30x e imagens representativas foram obtidas em MEV. Os valores de resistência à tração das amostras feitas com compósito à base de metacrilato e reparadas com compósito à base de metacrilato (G1 e G2) foram maiores do que nas amostras feitas com compósito à base de silorano e reparadas nas mesmas condições (G3 e G4). A termociclagem diminuiu os valores de resistência à tração para ambos os compósitos. Todos os grupos mostraram predominância de fraturas adesivas e nenhuma falha coesiva foi observada em compósito. Em conclusão, valores maiores de resistência à tração foram observados em amostras de resina à base de metacrilato e maior porcentagem de fraturas adesivas nas amostras de resina à base de silorano, ambos os compósitos reparados com resina à base de metacrilato.

Monomers used in resin composites: degree of conversion, mechanical properties and water sorption/solubility

The organic phase of resin composites is constituted by dimethacrylate resins, the most common monomers being the bisphenol A diglycidildimethacrylate (BisGMA), its ethoxylated version (BisEMA), triethylene glycol dimethacrylate (TEGDMA) and urethane dimethacrylate (UDMA). This study compared the homopolymers formed from the monomers used in restorative dental composites in terms of their degree of conversion (DC) and reaction kinetics (by near infra-red spectroscopy, n=3), mechanical properties (flexural modulus and strength in three point-bending, FM and FS, respectively, n=15), water sorption and solubility (WS and SL, respectively - ISO 4049, n=5). Materials were made photopolymerizable by the addition of camphoroquinone/dimethylamine ethyl methacrylate. TEGDMA showed the highest DC, followed by BisEMA, UDMA and BisGMA, both at 10 min and at 24h (p<0.001). UDMA showed the highest rate of polymerization, followed by TEGDMA, BisEMA and BisGMA (H0=13.254, p<0.001). UDMA and TEGDMA presented similar FM, significantly higher (p<0.001) than BisEMA and BisGMA, which in turn present statistically similar values (p>0.001). For FS, UDMA presented the highest value (p<0.001), followed by TEGDMA, then by BisEMA and BisGMA, which were statistically similar (p>0.001). BisGMA showed the highest WS, and TEGDMA and BisEMA the lowest. UDMA was statistically similar to all (H0=16.074, p<0.001). TEGDMA presented the highest SL, followed by UDMA, BisGMA and BisEMA (p<0.001). The tested homopolymers presented different behaviors in terms of polymerization kinetics, flexural properties, water sorption and solubility. Therefore, the use of copolymers is justified in order to obtain high DC and mechanical properties, as well as good resistance to water degradation.

A fase orgânica de compósitos resinosos é constituída por dimetacrilatos, sendo os mais comuns o dimetacrilato de diglicidilabisfenol A (BisGMA), sua versão etoxilada (BisEMA), dimetacrilato de trietilenoglicol (TEGDMA) e dimetacrilato de uretano (UDMA). Este estudo comparou os homopolímeros formados pelos monômeros utilizados em compósitos restauradores dentários em relação a seus graus de conversão (GC) e cinética de reação (através de espectroscopia no infra-vermelho), propriedades mecânicas (módulo de elasticidade em flexão e resistência à flexão, MF e RF, respectivamente), sorção de água e solubilidade (SA e SL, respectivamente - ISO4049). Os materiais se tornaram fotopolimerizáveis pela adição de canforoquinona/metacrilato de dimetilaminoetila e foram fotoativados utilizando uma fonte de luz de quartzo-tungstênio-halogênio filtrada para 400-500 nm. O TEGDMA apresentou o maior GC, seguido pelo BisEMA, UDMA e BisGMA, tanto aos 10 min quanto após 24 h (p<0,001). O UDMA mostrou a maior velocidade de reação, seguido pelo TEGDMA, BisEMA e BisGMA (H0=13,254, p<0,001). O UDMA e o TEGDMA apresentaram MF semelhantes, estatisticamente superiores ao BisEMA e ao BisGMA (p<0,001), os quais por sua vez apresentaram valores estatisticamente semelhantes (p>0,001). Para RF, o UDMA apresentou o valor mais alto, seguido pelo TEGDMA, BisEMA e BisGMA (p<0,001), sendo os dois últimos estatisticamente semelhantes (p>0,001). O BisGMA apresentou a maior SA, e o TEGDMA e o BisEMA as menores. O UDMA foi estatisticamente semelhante a todos (H0=16,074, p<0,001). O TEGDMA apresentou a maior SL, seguido pelo UDMA, BisGMA e BisEMA (p<0,001). Os homopolímeros demonstraram desempenhos bastante distintos em relação à cinética de polimerização, propriedades em flexão e sorção e solubilidade. Tais diferenças justificam o uso de co-polímeros para a obtenção de materiais com propriedades físicas otimizadas.