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Yao Xue Xue Bao ; (12): 663-667, 2005.
Article de Chinois | WPRIM | ID: wpr-353453

RÉSUMÉ

<p><b>AIM</b>To study the binding mode of balofloxacin with DNA and evaluate the influence of Mg2+ on the binding between balofloxacin and DNA.</p><p><b>METHODS</b>Fluorescent spectroscopy was used to study the interaction of balofloxacin with DNA and to calculate the thermodynamic constants. UV-Vis spectra, DNA viscosity titration, competition experiment and the effect of dsDNA and ssDNA on the fluorescense intensity were used to identify the binding mode.</p><p><b>RESULTS</b>Balofloxacin interacted with CT-DNA with a quenching constant of (5.43 +/- 0.07) x 10(3) L x mol(-1). The interaction was exothermic with a Van't Hoff enthalply of - 8.03 kJ x mol(-1) x Mg2+ cation could enhance the quenching constant between balofloxacin and DNA.</p><p><b>CONCLUSION</b>Balofloxacin interacted with CT-DNA in the mode of groove binding and Mg2+ could mediate the binding of balofloxacin to DNA.</p>


Sujet(s)
Animaux , Bovins , ADN , Chimie , Fluoroquinolones , Chimie , Magnésium , Chimie , Spectrométrie de fluorescence , Spectrophotométrie UV , Thermodynamique
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