Résumé
Antioxidant activity of dry ground rosemary [Rosmarinus officinalis L.] leaves of particle size = 70 micro m in purified corn and soybean oils triacylglycerols [CO TAG, SO TAG] was studied at 60 +/- 1 °C in dark. The systems were purified corn or purified soybean triacylglycerols without antioxidants [controls], with 100 micromole alpha tocopherol, 100 micromole butylated hydroxyanisol [BHA], 100 micromole butylated hydroxytoluene [BHT], 100 micromole tertbutyl hydroquinone [TBHQ], 100 micromole Trolox, 180 ppm carnosic acid and 0.2% ground rosemary leaves [filtered and non-filtered]. Oxidation was followed up by ferrous oxidation [Thiocyanate method] and hexanal determination. Diffusion of antioxidant constituents from rosemary into oil was monitored by radical scavenging method using alpha, alpha'-biphenyl-beta-picrylhydrazyl [DPPH]. Rosemary showed to be an effective antioxidant bearing plant especially with oils containing high percentage of polyunsaturated fatty acids. In CO TAG the order of decreasing hydroperoxide inhibition was Trolox >/= rosemary> TBHQ> carnosic> alpha-tocopherol> BHA. In SO TAG the inhibiton order was rosemary > Trolox> TBHQ>carnosic>alpha-tocopherol>BHA
Sujets)
Huile de soja , Huile de maïs , Antioxydants , alpha-Tocophérol , Feuilles de plante , Extraits de plantes , Chromatographie en phase liquide à haute performance , TriglycérideRésumé
Stripped soybean oil was used to investigate the effect of different packaging materials on photooxidation stability. Four packaging materials were used, two glass [clear and amber] and two plastic [low density polyethelene PE and polyethylene terephthalate PET]. Clear glass caused the highest hydroperoxide formation followed by PE and PET while amber glass caused the least one, since it excluded most of the incident light responsible for photoxidation, hence retarding it and decreasing off-flavour development. Also polyethylene terephthalate gave more inhibition of hydroperoxide than polyethylene. Polyethylene and polyethylene terephthalate packaging materials although they cause some of their constituents to migrate into edible oils, the over all amount migrated from them still below the international permitted level
Sujets)
Emballage alimentaire , Produits manufacturés/effets indésirables , Photosensibilisants , Verre , Matières plastiquesRésumé
Three different spent clay samples named spent clay produced from bleaching of hydrogenated oil [I], spent clay produced from bleaching of oil then filtered through normal non closed filter [II] and spent clay produced from bleaching of oil then filtered through closed filter [III] were available from the Extracted Oil Company and investigated in laboratory. Many factors like the effects of different solvents, time of extraction, temperature of heating and solvent to clay ratio on the percentage of oil extracted were investigated. The aim of this study is to estimate the optimum conditions for recovering the maximum oil as a waste of oil industry from the spent clay. The authors found that n-hexane and petroleum ether 60/80 at 70°C, 6 hr heating and clay [solid]: solvent [liquid] ratio 5:95 w/v gave the highest percentage of oil recovery. The physical and chemical characteristics of the oils of the three samples were determined. The results indicated using these oils for industrial purposes
Sujets)
Matières grasses , Extractions en série , Huiles végétales/composition chimique , Solvants , Hexanes , Facteurs temps , PétroleRésumé
Phospholipid mixtures were isolated from crude soybean oil and laboratory prepared soy lecithin were fractionated on two silicic acid columns with subsequent thin layer chromatography identification of isolated fractions. The percentages of the isolated four eluted fractions from each of the two columns were calculated. Phosphatidylcholine, phosphatidylethanolamine phosphatidylinositol, phosphatidic acid and cerebroside were isolated. Fatty acid composition and total phosphorus of the isolated phospholipids were determined