1.
Mem. Inst. Oswaldo Cruz
;
86(supl.2): 117-120, 1991. ilus
Artigo
em Inglês
| LILACS
| ID: lil-623953
RESUMO
An efficient (12 steps, 12% overallyield) and stereoselective total synthesis of (±)-serricornine (1) the sex pheromone of the cigarette beetle (Lasioderma serricornine F) is described. The preparation of intermediate 5, which encompasses the proper relative configuration of three contiguous chiral centers of (±)-invictolide, (3), is discussed.