[Reaction kinetics of aniline synthetic wastewater treatment by moving bed bioflim reactor]

ABSTRACT

Experiments were conducted to investigate the behavior of Moving Bed Bioflim Reactor [MBBR] as a novel aerobic process for treatment of aniline synthetic wastewater as a hard biodegradable compound is commonly used in number of industrial processes. The objective of this paper is evaluation of MBBR in different conditions for treatment of aniline and determination of reaction kinetics. In the MBBRs, different carriers are used to maximize the active biofilm surface area in the reactors. In this study, the reactor was filled with Light Expanded Clay Aggregate [LECA] as carriers. Evaluation of the reactor efficiency was done at different retention time of 8, 24, 48 and 72 hours with an influent COD from 100 to 3500 mg/L [filling ratio of 50%]. After obtaining removal efficiencies, effluent concentration of aniline was measured by adsorption spectrum and maladaptive municipal wastewater treatment plant sludge in batch conditions for confidence of aniline biodegradation and its adsorption to the sludge mass. The maximum obtained removal efficiencies were 91% [influent COD=2000 mg/L] after 72 hours. Biodegradation of aniline in MBBR has been also approved by NMR spectrum tests. Finally experimental data has indicated that Grau second order model and Stover-Kincannon were the best models to describe substrate loading removal rate for aniline. MBBR as an advanced biological process had a proper COD removal efficiency for the biological treatment of aniline wastewater compared to other researchers methods: