Rearrangement of benzylideneacetophenone oxide with sodium phonate in aprotic solvents
Egyptian Journal of Chemistry. 1991; 34 (3): 181-88
in English
| IMEMR
| ID: emr-107480
ABSTRACT
Treatment of benzylideneacetophenone oxide [1] with sodium phenoxide in acetonitrile or dioxan gave 2-benzoyl-3, 4 acid type rearrangement. The reaction of III with halogeno acids gave 2, 3, 4, 6-tetraphenyl 1-2 H-pyran-2-carboxylic acid [VI]. The structure of the products was assigned by chemical and spectroscopic methods:
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Index:
IMEMR (Eastern Mediterranean)
Main subject:
Solvents
Language:
English
Journal:
Egypt. J. Chem.
Year:
1991
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