Rubber and methane recovery from deproteinized natural rubber wastewater by coagulation pre-treatment and anaerobic treatment

ABSTRACT

A newly developed natural rubber deproteinization process produces deproteinized natural rubber [DPNR] wastewater as an intermediate product containing a high concentration of sodium dodecyl sulfate [SDS] and rubber. In this study, a novel process to recover the residual rubber and energy as methane from DPNR wastewater was developed. As a pretreatment, SDS and residual rubber in DPNR wastewater were coagulated and recovered by addition of CaCl[2] at Ca[2+]/SDS and Ca[2+]/rubber mass ratios of 0.070 and 0.055, respectively. The remaining organic matter in the pre-treated DPNR wastewater was converted to methane by using a mesophilic up-flow anaerobic sludge bed [UASB] reactor. The UASB reactor with the diluted pre-treated DPNR wastewater showed a total chemical oxygen demand [COD] removal efficiency of 92 +/- 2% at a maximum loading rate of 6.8 +/- 1.8 kgCODm[-3]d[-1] at a hydraulic retention time [HRT] of 12 h. Under the condition of effluent recirculation with raw pre-treated DPNR wastewater, the UASB reactor showed a total COD removal efficiency of 84 +/- 8% at the maximum loading rate of 6.4 +/- 1.7 kgCODm[-3]d[-1] at HRT of 39 h. The results suggest that the newly developed resource recovery process for DPNR wastewater could be a promising treatment system