Kinetics of epoxidering opening
Bulletin of the Faculty of Science-University of Alexandria. 1991; 31[B]: 36-46
in English
| IMEMR
| ID: emr-19472
ABSTRACT
The rates of the reactions of some trans -epoxy-p-substituted benzalacetophenones with morpholine in acetonitrile have been measured at different temperatures. The reactions are second order and proceed via S[N2]-like mechanism to give the corresponding alpha-hydroxy-beta -morpholino- beta- [p-substituted phenyl] propiophenones. Effect of substituents has in terms of Hammett linear free energy relationship
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Index:
IMEMR (Eastern Mediterranean)
Main subject:
Kinetics
Language:
English
Journal:
Bull. Fac. Sci.-Univ. Alex.
Year:
1991
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