4-Trifluoromethylbenzyl chloride: preparation kinetics and mechanism of its change into bis [4-trifluoromethylbenzyl] ether in alkaline dioxane-water media
Egyptian Journal of Chemistry. 1994; 37 (2): 123-130
in English
| IMEMR
| ID: emr-32435
ABSTRACT
The expected alpha-proton abstraction step from the title compound by alkali in dioxane-water media, due to the electron-withdrawing 4-trifluoromethyl group, does not take place instead an S [N]2 reaction followed by an etherification step occurs. This consecutive reaction was studied kinetically in different dioxane-water media at various temperatures
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Index:
IMEMR (Eastern Mediterranean)
Main subject:
Kinetics
Language:
English
Journal:
Egypt. J. Chem.
Year:
1994
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