Structural and specific solvent effects on the kinetics of Alkaline hydrolysis of methylacrylate and methylmethacrylate esters
Egyptian Journal of Chemistry. 2001; 44 (1-3): 33-50
in English
| IMEMR
| ID: emr-56671
ABSTRACT
The rates of alkaline hydrolysis of methyl prop-2-enoic acid [methylacrylate] 1 and methyl-2-methyl-prop-2-enoic acid [methylmethacrylate] 2 were studied at temperatures ranging from 10 to 35 degree in two series of dioxane-water and acetone-water mixtures containing 10 to 75 percent by volume of the organic component. The rate constants were found to be higher in acetone-water mixtures and decreased with increasing the dielectric constant of the medium. The kinetic studies and application of the differential method show that the rate follows a second order kinetic equation, first order with respect to both ester and hydroxide ion and the reaction proceeds by a B[Ac2] mechanism. The distance of closest approach of solvent molecules to the activated complex b and the distance of closest approach of solvent molecules to the transition state G were computed
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Index:
IMEMR (Eastern Mediterranean)
Main subject:
Solvents
/
Temperature
/
Kinetics
/
Dioxanes
/
Esters
/
Methylmethacrylates
Language:
English
Journal:
Egypt. J. Chem.
Year:
2001
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