Reactivity of 4,6-diacetylcyclohexenones towards some nucleophilic reagents
Egyptian Journal of Chemistry. 1986; 29 (4): 485-93
in English
| IMEMR
| ID: emr-7164
ABSTRACT
It has been reported, acetylacetone easily condensed with chalcone under Michael conditions to give the corresponding cyclohexenone derivative. Thus, condensation of acetylacetone with mono-arylidene-acetylacetone I [a and b] in the presence of sodium ethoxide afforded the formation of tetraketone addition products I la and b or the corresponding cyclohexenone derivatives IIIa and b depending on the reaction conditions. Reaction of acetylacetone with I in the presence of sodium ethoxide solution at room temperature gave rise to the corresponding Michael addition products II [a and b] respectively
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Index:
IMEMR (Eastern Mediterranean)
Language:
English
Journal:
Egypt. J. Chem.
Year:
1986
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