Simultaneous determination of bisphenols and alkylphenols in water by solid phase extraction and ultra performance liquid chromatography-tandem mass spectrometry / 生物医学与环境科学(英文)
Biomedical and Environmental Sciences
;
(12): 471-474, 2014.
Article
in English
| WPRIM
| ID: wpr-270578
ABSTRACT
To establish an analytical method for determination of four bisphenols (BPA, BPB, BPF, and BPS) and two alkylphenols (4-n-OP, 4-n-NP) in water by ultra performance liquid chromatography- tandem mass spectrometry (UPLC/MS/MS). The water samples were extracted and condensed with solid-phase extraction (SPE) using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0 μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%. Relative standard deviations (RSDs) were between 1.26% and 3.67%. Applying this method to detect the source water of Chaohu Lake and drinking water of Hefei, six target compounds were detected in different levels. This method is simple with high sensitivity and selectivity, could be suitable for the determination of these compounds in source and drinking water.
Full text:
Available
Index:
WPRIM (Western Pacific)
Main subject:
Phenols
/
Water Pollutants, Chemical
/
Chromatography, Liquid
/
Endocrine Disruptors
/
Tandem Mass Spectrometry
/
Solid Phase Extraction
Language:
English
Journal:
Biomedical and Environmental Sciences
Year:
2014
Type:
Article
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