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Investigation on formation mechanism of secologanic acid sulfonates in sulfur-fumigated buds of Lonicera japonica / 中国中药杂志
China Journal of Chinese Materia Medica ; (24): 1639-1643, 2014.
Article in Chinese | WPRIM | ID: wpr-300214
ABSTRACT
To investigate formation mechanism of secologanic acid sulfonates in sulfur-fumigated buds of Lonicera japonica, secologanic acid was enriched and purified from the sun-dried buds of L. japonica by various column chromatography on macroporus resin HPD-100, silica gel and ODS. The stimulation experiments of sulfur-fumigation process were carried out using secologanic acid reacted with SO2 in the aqueous solution. The reaction mechanism could be involved in the esterification or addition reaction. The present investigation provides substantial evidences for interpreting formation pathway of secologanic acid sulfonates in sulfur-fumigated buds of L. japonica.
Subject(s)
Full text: Available Index: WPRIM (Western Pacific) Main subject: Pharmacology / Sulfur / Sulfur Dioxide / Carboxylic Acids / Water / Molecular Structure / Chemistry / Chromatography, High Pressure Liquid / Alkanesulfonates / Lonicera Language: Chinese Journal: China Journal of Chinese Materia Medica Year: 2014 Type: Article

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Full text: Available Index: WPRIM (Western Pacific) Main subject: Pharmacology / Sulfur / Sulfur Dioxide / Carboxylic Acids / Water / Molecular Structure / Chemistry / Chromatography, High Pressure Liquid / Alkanesulfonates / Lonicera Language: Chinese Journal: China Journal of Chinese Materia Medica Year: 2014 Type: Article