Application of activated carbon-decorated polyacrylonitrile nanofibers as an adsorbent in dispersive solid-phase extraction of fluoroquinolones from wastewater / 药物分析学报

ABSTRACT

A cheap and simple sample preparation method, consisting of a dispersive solid-phase method and an ad-sorbent, activated carbon decorated PAN nanofibers, was employed and used for the extraction of antibiotics (ciprofloxacin, danofloxacin, and enrofloxacin) in wastewater. Electrospun PAN nanofibers that were deco-rated with activated carbon produced from waste tires were used as the solid phase and the antibiotics analyzed by using high-performance liquid chromatography. Parameters such as pH, mass of adsorbent (MA), extraction volume (EV), and extraction time (ET) were optimized owing to their potential effect on the extraction of antibiotics from water. The recovery of all antibiotics was satisfactory, in the range of 90％–99％. The limits of detection and quantification were 0.05, 0.11, 0.20, and 0.53, 1.21, 2.17 μg/L, respectively. The precision was determined from the repeatability and reproducibility and expressed as the intra-day (n = 20) and inter-day (n = 5) precision. The intra-day and inter-day precision was reported in terms of the per-centage relative standard deviation, which was 3％ and 4％, respectively. The adsorption capacity of the ac-tivated carbon-decorated PAN nanofibers was satisfactory, and the reusability of the adsorbent was im-pressive when reused ten times. The accuracy of the dispersive solid phase extraction (DSPE) was validated by spike recovery tests; the results proved the reliability and efficiency of adsorbing antibiotics from was-tewater. Finally, the proposed method was applied to wastewater samples collected from a wastewater treatment plant, which included influent, secondary, and effluent wastewater.