Asymmetric hydrogenation of methyl-2-acylamino-3-arylacrylate / 中国药科大学学报
Journal of China Pharmaceutical University
;
(6): 553-557, 2018.
Article
in Chinese
| WPRIM
| ID: wpr-811756
ABSTRACT
@#By using(S)-MonoPHOS and [Rh(COD)2]BF4 as catalyst, the asymmetric hydrogenation reactions of methyl-2-acylamino-3-arylacrylate and the effect of different amino protective groups on hydrogenation efficacy were studied. The products resulting from asymmetric hydrogenation were hydrolyzed by hydrochloric acid, and the corresponding amino acids were obtained at yields of 63%- 92%.
Full text:
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Index:
WPRIM (Western Pacific)
Language:
Chinese
Journal:
Journal of China Pharmaceutical University
Year:
2018
Type:
Article
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