Adsorption Properties of Thermally Treated Rice Husk for Removal of Sulfamethazine Antibiotic from Pharmaceutical Wastewater

ABSTRACT

Equilibrium sorption of the Thermally Treated Rice Husk (TTRH) for Sulfamethazine (SMT) adsorption was studied. The Physico-chemical properties of the modified rice husk were determined. The equilibrium sorption data were fitted into Langmuir, Freundlich and Dubinin–Radushkevich isotherms. Of the three adsorption isotherm, the R2value of Langmuir isotherm model was the highest. Also compared to other isotherms the AARE coefficient for the Langmuir isotherm is low,which indicates favorable sorption. The maximum monolayer coverage (qm) from Langmuir isotherm model was determined to be 19.11 mg/g, the separation factor indicating a favorable sorption experiment is 0.446. Also from Freundlich Isotherm model, the sorption intensity (n) which indicates favorable sorption andthe correlation value are 1.84 and 3.79 respectively. The mean free energy was estimated from Dubinin–Radushkevich isotherm model to be 9.18 KJ/mol which clearly proved that the adsorption experiment followed a physical process