Determination of Depolymerization Products in Supercritic al Methanolysis of Poly(ethylene terephthalate)polyester by Reversed Phase High Performance Liquid Chromatography / 分析化学
Chinese Journal of Analytical Chemistry
;
(12): 676-678, 2001.
Artículo
en Chino
| WPRIM
| ID: wpr-410231
ABSTRACT
qualitative and quantitative analysis of solid depolymerization products for supercritical methanolysis of ploy(ethylene terephthalate) polyester (PET) were studied by means of reversedphase high performance liquid chromatogr aphy on ZorbaxC8(4.6mm×250mm) with 70%(V/V) methanol as mobile phase. The results showed that the solid depolymerization products were mainly composed of dimethyl terephthalate (DMT), methyl(2hydroxyethyl)terephthalate (MHET), bis(hydroxyethyl)tere phthalate (BHET), dimers and oligomers, which could be separated effectively under the above chromatographic conditions. The calibration curves of DMT and BHET were linear in the range of 1.0~45 mg/L (n=8),r=0.9998~1.0000 and RSD<2.8%. The determination limits of DMT and BHET were 4.0×10-4μg and 6.0×10-4μg respectively.
Texto completo:
Disponible
Índice:
WPRIM (Pacífico Occidental)
Tipo de estudio:
Investigación cualitativa
Idioma:
Chino
Revista:
Chinese Journal of Analytical Chemistry
Año:
2001
Tipo del documento:
Artículo
Similares
MEDLINE
...
LILACS
LIS