[Performance of simple nano zeolite Y and modified nano zeolite Y in phosphor removal from aqueous solutions]

ABSTRACT

Phosphate discharges from domestic and industrial waste water to water bodies. High concentrations of phosphate in water stimulate the eutrophication phenomenon that causes taste and odor in water, losing dissolved oxygen and aquatic life in rivers or surface waters. Aim of this study is survey of phosphate adsorption on simple nano zeolite Y and nano zeolite Y that was modified with a cationic surfactant [HDTMA-Br]. In This study we used simple nano zeolite Y and nano zeolite Y in form of Surfactant Modified Zeolites [SMZs] using batch tests to adsorption of Phosphate from Aqueous Solutions. The adsorbants were contacted with different initial phosphor concentrations [5, 10 and 15 mg/l], pH [4, 7, 12], contact time [30, 60, 90, 120, 150 and 180 minutes] and weight of adsorbant [0.2, 0.4, 0.6, 0.8 and 1g]. the extracted solution was determined for Phosphate concentration by the ammonium molybdate and tin chloride method with spectrophotometric detection at 680 nm. Results of this study show that, with increase in contact time, decrease in pH, increase in zeolites concentration and decrease in initial phosphate concentration, the removal efficiency increased. And the Both isotherm of Langmuir and Freundlich models [r[2]>0.997 and r[2]>0.996 respectively] were agreement with adsorption equilibrium of phosphate. Reduced Chi-Sqr For Langmuir and Freundlich models were [0.00079] and [0.0011] respectively. Pseudo first-order kinetic models fits well with experimental data [r[2]>0.963]. From this survey, it is concluded that performance of modified nano zeolite Y for adsorption of phosphate in same conditions is better than non-modified zeolite Y. In general the modified nano zeolite Y presented a good profile for removal of phosphate. Therefore SMZs is a suitable candidate for removal of Phosphate molecules from contaminated solutions in contaminated waters