[Photocatalytic removal of hexavalent chromium and divalent nickel from aqueous solution by UV irradiation in the presence of titanium dioxide nanoparticles]

ABSTRACT

Industrial wastewater included the heavy metal is one of the important sources of environmental pollution. Hexavalent chromium and divalent nickel are founded in plating wastewater which is harmful for human health and environment. Therefore, the purpose of this research is investigation of photocatalytic removal of hexavalent chromium and divalent nickel from aqueous solution using UV/TiO[2] process in a batch system. At first, reactor was designed. Then, optimumdosage of TiO[2] was obtained equal to 1 g/L, with variation TiO[2] dosage at constant pH and initial concentrations of hexavalent chromium and divalent nickel. The effect of pH, contact time and initial concentration of hexavalent chromium was studied at the constant amount of TiO[2] [1gr/L]. The result showed that photocatalytic removal efficiency increased with increasing reaction time and TiO[2] dosage. In addition, it was found that removal efficiency of hexavalent chromium was decreased by increasing initial chromium concentration and pH. But, photocatalytic removal efficiency of nickel ion was increased and decreased by increasing of pH and initial nickel concentration, respectively. The results showed that UV/TiO[2] was an effective method in removal of hexavalent chromium and divalent nickel from aqueous solutions