4-Trifluoromethylbenzyl chloride: preparation kinetics and mechanism of its change into bis [4-trifluoromethylbenzyl] ether in alkaline dioxane-water media
Egyptian Journal of Chemistry. 1994; 37 (2): 123-130
em Inglês
| IMEMR
| ID: emr-32435
ABSTRACT
The expected alpha-proton abstraction step from the title compound by alkali in dioxane-water media, due to the electron-withdrawing 4-trifluoromethyl group, does not take place instead an S [N]2 reaction followed by an etherification step occurs. This consecutive reaction was studied kinetically in different dioxane-water media at various temperatures
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Índice:
IMEMR (Mediterrâneo Oriental)
Assunto principal:
Cinética
Idioma:
Inglês
Revista:
Egypt. J. Chem.
Ano de publicação:
1994
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