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Supramolecular photochemistry and solar cells
Iha, Neyde Yukie.
  • Iha, Neyde Yukie; Universidade de Säo Paulo. Instituto de Química. Laboratório de fotoquímica Inorgânica e Conversäo de Energia.
An. acad. bras. ciênc ; 72(1): 67-73, mar. 2000.
Artigo em Inglês | LILACS | ID: lil-259480
RESUMO
Supramolecular photochemistry as well as solar cells are fascinating topics of current interest in Inorganic Photochemistry and very active research fields which have attracted wide attention in last two decades. A brief outline of the investigations in these fields carried out in our Laboratory of Inorganic Photochemistry and Energy Conversion is given here with no attempt of an exhaustive coverage of the literature. The emphasis is placed on recent work and information on the above mentioned subjects. Three types of supramolecular systems have been the focus of this work (i) cage-type coordination compounds; (ii) second-sphere coordination compounds, exemplified by ion-pair photochemistry of cobalt complexes and (iii) covalently-linked systems. In the latter, modulation of the photoluminescence and photochemistry of some rhenium complexes are discussed. Solar energy conversion and development of thin-layer photoelectrochemical solar cells based on sensitization of nanocrystalline semiconductor films by some ruthenium polypyridyl complexes are presented as an important application that resulted from specifically engineered artificial assemblies.
Assuntos
Texto completo: DisponíveL Índice: LILACS (Américas) Assunto principal: Fotoquímica / Fontes de Energia Elétrica / Energia Solar Idioma: Inglês Revista: An. acad. bras. ciênc Assunto da revista: Ciência Ano de publicação: 2000 Tipo de documento: Artigo

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Texto completo: DisponíveL Índice: LILACS (Américas) Assunto principal: Fotoquímica / Fontes de Energia Elétrica / Energia Solar Idioma: Inglês Revista: An. acad. bras. ciênc Assunto da revista: Ciência Ano de publicação: 2000 Tipo de documento: Artigo