Determination of epichlorohydrin in workplace air by gas chromatograph-electron capture detector / 中华劳动卫生职业病杂志

ABSTRACT

<p><b>OBJECTIVE</b>To develop a method for determining epichlorohydrin in the workplace air by gas chromatograph-electron capture detector (GC-ECD).</p><p><b>METHODS</b>Epichlorohydrin in the workplace air was collected by activated charcoal tubes, desorbed using acetone, and analyzed by GC-ECD.</p><p><b>RESULTS</b>A good linearity was obtained in the range of 1.0-50 µg/mL (r=0.999 7). The detection limit was 0.012 µg/ml, while the recovery rate was 88.1% and relative standard deviation ranged from 1.11% to 3.57%. The samples could be stored for seven days at room temperature.</p><p><b>CONCLUSION</b>This method effectively eliminates the interferences of alkanes on determination of epichlorohydrin and improves the sensitivity by 1 to 2 orders of magnitude, which can solve the problem of detection limit above standard in GBZ/T 160.58-2004.</p>