Evaluation of effluent post-treatment by slow filtration and adsorption with activated carbon produced from spent coffee grounds in surfactant removal in sewage treatment

ABSTRACT

Environmental pollution is a worldwide concern, especially when caused by sewage dumping into water bodies. Many substances are present in industrial or domestic wastewater, causing contamination in superficial water collection. Surfactants stand out for being widely used both industrially and domestically. The use of detergents and many types of surfactants was increased during the Covid-19 pandemic period, a fact observed in the levels in the effluent sample analysis from a Sewage Treatment Plant (STP) - Vila City around 21 and 39 mg L-1 in this period. This work evaluated the surfactant concentrations in the primary and secondary treatment units of the Vila City STP, in the city of Paranavaí-PR.-Brazil. In addition, the use of a post-treatment by slow sand filtration and adsorption by activated carbon produced from spent coffee grounds in the complementary removal of surfactants was proposed. A mixed bed with sand and activated carbon columns was made on a pilot scale, and filtration/adsorption runs were performed simulating slow filtration with rates of approximately 15 m3 m-2 day-1. The parameters used for the efficiency removal evaluation in a pilot plant run were turbidity (NTU) and surfactant concentrations. The removal of surfactant concentrations was about 9% and 7% in the Upflow Anaerobic Sludge Bed reactors (UASB-RALF) and in the secondary treatment, respectively, at the STP - Vila City units. In the post-treatment proposed by filtration/adsorption, bed columns on a pilot scale plant obtained a reduction of approximately 94% in terms of turbidity (NTU) and 95% in terms of surfactant removal.AlternatePoluiçâo ambiental é uma preocupaçâo mundial, especialmente causada por despejos de esgotos nos coleçâo hídrica. Diversas substancias compöem os despejos e residuos industriais e esgotos domésticos. Os surfactantes destacam-se por serem amplamente usados tanto industrialmente como domesticamente. O consumo de detergentes e diversos tipos de tensoativos foi incrementado durante o período de pandemia da Covid-19, fato observado nos teores de surfactantes no efluente das Estaçöes de Tratamento de Esgoto (ETE) - Vila City entre 21 e 39 mg L-1 neste período de tempo. Este trabalho avaliou as concentraçöes de surfactantes em diferentes etapas da ETE da Vila City, na cidade de Paranavaí, PR.- Brasil. Além disso, propôs-se a utilizaçao de um pós-tratamento por filtraçâo/adsorçâo por carvão ativado produzido a partir da borra de café na remoçao complementar dos surfactantes. Foram confeccionadas colunas de adsorçao com meio filtrante de areia e carvão em escala piloto e realizados ensaios de filtração/adsorção simulando filtração lenta com taxas de aproximadamente 15 m3 m-2 dia-1. Os parámetros utilizados na aval