Impact of COVID-19 Pandemic Lockdown in Ambient Concentrations of Aromatic Volatile Organic Compounds in a Metropolitan City of Western India.

ABSTRACT

The real-time Benzene, Toluene, Ethylbenzene, and Xylenes (BTEX) concentrations were measured in a metropolitan city of India during January to May of 2020 and 2014-2015-2018 to assess the impact of emission reduction during the COVID-19 lockdown. The total BTEX (∑BTEX) concentrations were 11.5 ± 9.0, 15.7 ± 16, 5.3 ± 5.0, 2.9 ± 2.0, and 0.93 ± 1.2 ppbv in January-May 2020, respectively. The evening rush hour peaks of BTEX during lockdown decreased by 4-5 times from the same period of years 2014-2015-2018. A significant decline in background concentrations suggests a regional-scale reduction in anthropogenic emissions. The contributions of ∑TEX compounds to ∑BTEX increased from 42% to 59% in winter to 64%-75% during the lockdown under hot summer conditions. While emission reductions dominated during the lockdown period, the meteorological and photochemical factors may also have contributed. Meteorological influence on actual observed BTEX data was removed by normalizing with ventilation coefficient (VC). The actual ambient air reductions of 85%-90% and VC-normalized reductions of 54%-88% of the BTEX concentrations during lockdown were estimated compared to those during the same period of 2014-2015-2018. The estimated changes using nighttime data, which take into account BTEX photooxidation removal, are ∼8% lower than the VC-normalized estimates using all data. These significant reductions in BTEX concentrations are consistent with the change in people's movement as inferred from mobility data during the lockdown. Although enforced, the significant decline in ambient BTEX levels during lockdown was a good change for the air quality. The study suggests a need for more effective science-based policies that consider local and regional factors.