Detalles de la búsqueda
1.
Substituent Effects on the [N-I-N](+) Halogen Bond.
J Am Chem Soc
; 138(31): 9853-63, 2016 08 10.
Artículo
en Inglés
| MEDLINE | ID: mdl-27265247
2.
Cu(II)-promoted methanolysis of N,N-bis(2-picolyl)carbamates: rate-limiting metal ion delivery of coordinated alcoholate nucleophile followed by fast partitioning of a tetrahedral intermediate.
J Org Chem
; 80(3): 1357-64, 2015 Feb 06.
Artículo
en Inglés
| MEDLINE | ID: mdl-25553487
3.
Cu(II)-ion-catalyzed solvolysis of N,N-bis(2-picolyl)ureas in alcohol solvents: evidence for cleavage involving nucleophilic addition and strong assistance of bis(2-picolyl)amine leaving group departure.
Inorg Chem
; 53(15): 7916-25, 2014 Aug 04.
Artículo
en Inglés
| MEDLINE | ID: mdl-25054275
4.
Rapid Ni, Zn, and Cu ion-promoted alcoholysis of N,N-bis(2-picolyl)- and N,N-bis((1H-benzimidazol-2-yl)methyl)-p-nitrobenzamides in methanol and ethanol.
Inorg Chem
; 53(4): 2211-21, 2014 Feb 17.
Artículo
en Inglés
| MEDLINE | ID: mdl-24491210
5.
Cu(II)-promoted methanolysis of N,N-dipicolylacetamide. multistep activation by decoupling of > ÌÌN-CâO resonance via Cu(II)-N binding, delivery of the Cu(II):((-)OCH3) nucleophile, and metal ion assistance of the departure of the leaving group.
J Org Chem
; 77(8): 4156-60, 2012 Apr 20.
Artículo
en Inglés
| MEDLINE | ID: mdl-22439810
6.
Trifunctional metal ion-catalyzed solvolysis: Cu(II)-promoted methanolysis of N,N-bis(2-picolyl) benzamides involves unusual Lewis acid activation of substrate, delivery of coordinated nucleophile, powerful assistance of the leaving group departure.
Inorg Chem
; 51(19): 10325-33, 2012 Oct 01.
Artículo
en Inglés
| MEDLINE | ID: mdl-22971051
7.
Solvent induced cooperativity of Zn(II) complexes cleaving a phosphate diester RNA analog in methanol.
Org Biomol Chem
; 10(3): 631-9, 2012 Jan 21.
Artículo
en Inglés
| MEDLINE | ID: mdl-22116167
8.
Methanolysis of thioamide promoted by a simple palladacycle is accelerated by 10(8) over the methoxide-catalyzed reaction.
J Am Chem Soc
; 133(50): 20068-71, 2011 Dec 21.
Artículo
en Inglés
| MEDLINE | ID: mdl-22087539
9.
Study on the transesterification of methyl aryl phosphorothioates in methanol promoted by Cd(II), Mn(II), and a synthetic Pd(II) complex.
Inorg Chem
; 50(5): 1786-97, 2011 Mar 07.
Artículo
en Inglés
| MEDLINE | ID: mdl-21284376
10.
Palladacycle-promoted solvolytic cleavage of O,O-dimethyl O-aryl phosphorothioates. Converting a phosphorane-like transition state to an observable intermediate.
Inorg Chem
; 50(16): 7852-62, 2011 Aug 15.
Artículo
en Inglés
| MEDLINE | ID: mdl-21744816
11.
Demonstration of prominent Cu(II)-promoted leaving group stabilization of the cleavage of a homologous set of phosphate mono-, di-, and triesters in methanol.
J Am Chem Soc
; 132(10): 3561-73, 2010 Mar 17.
Artículo
en Inglés
| MEDLINE | ID: mdl-20163122
12.
Mechanistic and computational study of a palladacycle-catalyzed decomposition of a series of neutral phosphorothioate triesters in methanol.
J Am Chem Soc
; 132(46): 16599-609, 2010 Nov 24.
Artículo
en Inglés
| MEDLINE | ID: mdl-21033707
13.
On the question of stepwise vs. concerted cleavage of RNA models promoted by a synthetic dinuclear Zn(II) complex in methanol: implementation of a noncleavable phosphonate probe.
Org Biomol Chem
; 8(4): 822-7, 2010 Feb 21.
Artículo
en Inglés
| MEDLINE | ID: mdl-20135039
14.
Leaving group assistance in the La3+-catalyzed cleavage of dimethyl (o-methoxycarbonyl)aryl phosphate triesters in methanol.
J Am Chem Soc
; 131(38): 13738-48, 2009 Sep 30.
Artículo
en Inglés
| MEDLINE | ID: mdl-19736937
15.
Dinuclear Zn(II) complex promotes cleavage and isomerization of 2-hydroxypropyl alkyl phosphates by a common cyclic phosphate intermediate.
J Am Chem Soc
; 131(11): 4159-66, 2009 Mar 25.
Artículo
en Inglés
| MEDLINE | ID: mdl-19292494
16.
An immobilized ortho-palladated dimethylbenzylamine complex as an efficient catalyst for the methanolysis of phosphorothionate pesticides.
Inorg Chem
; 48(3): 1183-91, 2009 Feb 02.
Artículo
en Inglés
| MEDLINE | ID: mdl-19105733
17.
Investigation of the effect of oxy bridging groups in dinuclear Zn(II) complexes that catalyze the cleavage of a simple phosphate diester RNA analogue.
Inorg Chem
; 48(23): 11425-33, 2009 Dec 07.
Artículo
en Inglés
| MEDLINE | ID: mdl-19874005
18.
Enzyme-like acceleration for the hydrolysis of a DNA model promoted by a dinuclear Zn(II) catalyst in dilute aqueous ethanol.
J Am Chem Soc
; 130(42): 13870-2, 2008 Oct 22.
Artículo
en Inglés
| MEDLINE | ID: mdl-18821763
19.
A simple DNase model system comprising a dinuclear Zn(II) complex in methanol accelerates the cleavage of a series of methyl aryl phosphate diesters by 10(11)-10(13).
J Am Chem Soc
; 130(20): 6639-49, 2008 May 21.
Artículo
en Inglés
| MEDLINE | ID: mdl-18479083
20.
The dinuclear Zn(II) complex catalyzed cyclization of a series of 2-hydroxypropyl aryl phosphate RNA models: progressive change in mechanism from rate-limiting P-O bond cleavage to substrate binding.
J Am Chem Soc
; 129(51): 16238-48, 2007 Dec 26.
Artículo
en Inglés
| MEDLINE | ID: mdl-18047345