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1.
Phys Rev E ; 94(4-1): 042602, 2016 Oct.
Article in English | MEDLINE | ID: mdl-27841487

ABSTRACT

We study the dynamics of a probe particle driven by a constant force through a colloidal glass of hard spheres. This nonequilibrium and anisotropic problem is investigated using a new implementation of the mode-coupling approximation with multiple relaxation channels and Langevin dynamics simulations. A force threshold is found, below which the probe remains localized, while above it the probe acquires a finite velocity. We focus on the localized regime, comparing theory and simulations concerning the dynamics in the length scale of the cage and the properties of the transition to the delocalized regime, such as the critical power-law decay of the probe correlation function. Probe van Hove functions predicted by the theory show exponential tails reminiscent of an intermittent dynamics of the probe. This scenario is microscopically supported by simulations.

2.
J Chem Phys ; 128(9): 094502, 2008 Mar 07.
Article in English | MEDLINE | ID: mdl-18331102

ABSTRACT

The short-time self-diffusion coefficient of a sphere in a suspension of rigid rods is calculated in first order in the rod volume fraction phi. For low rod concentrations, the correction to the Einstein diffusion constant of the sphere due to the presence of rods is a linear function of phi with the slope alpha proportional to the equilibrium averaged mobility diminution trace of the sphere interacting with a single freely translating and rotating rod. The two-body hydrodynamic interactions are calculated using the so-called bead model in which the rod of aspect ratio p is replaced by a stiff linear chain of touching spheres. The interactions between spheres are calculated using the multipole method with the accuracy controlled by a multipole truncation order and limited only by the computational power. A remarkable accuracy is obtained already for the lowest truncation order, which enables calculations for very long rods, up to p=1000. Additionally, the bead model is checked by filling the rod with smaller spheres. This procedure shows that for longer rods the basic model provides reasonable results varying less than 5% from the model with filling. An analytical expression for alpha as a function of p is derived in the limit of very long rods. The higher order corrections depending on the applied model are computed numerically. An approximate expression is provided, valid for a wide range of aspect ratios.

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