Efficient dye removal from industrial wastewater using sustainable activated carbon and its polyamide nanocomposite derived from agricultural and industrial wastes in column systems.

Sugar beet crown (SBC) waste was employed to produce sustainable activated carbon (AC) by a thermo-chemical activation procedure using a fixed ratio of H3PO4/SBC (1 : 1 w/w ratio) at 550 °C/2 h. An activated carbon/polyamide nano-composite (AC/PA) was also prepared through the polymerization of the fabricated AC (90%) with polyamide (PA, 10%) synthetic textile waste using a proper dissolving agent at a specified w/w ratio with the employed polymer (formic acid/PA = 82/18%). Both AC and its derivative AC/PA were employed in the remediation of dyes from industrial wastewater in column systems, and their efficiencies were compared at various applied experimental conditions. The adsorption of the industrial dye waste (IDW) was a pH-, flow rate-, and bed thickness-controlled process by the regarded adsorbents. Kinetic studies confirmed the suitability of the Thomas equation over the Yoon and Nelson model in predicting the dynamic adsorption process of IDW by AC and AC/PA as was assured by the close agreement among the calculated and experimental uptake capacities of both adsorbents at the same applied flow rates, suggesting the chemisorption nature of IDW adsorption. Additionally, electrostatic attraction was the leading mechanism of IDW adsorption by AC and AC/PA composite with some advantages of the former over the latter.

Environmental Geochemistry and Fractionation of Cadmium Metal in Surficial Bottom Sediments and Water of the Nile River, Egypt.

Heavy metals such as cadmium (Cd) pollute the environment. Heavy metal pollution endangers the Nile River since it serves as an irrigation and freshwater source for the cities and farms that line its banks. Water and sediment samples from the Nile River were tested for Cd content. In addition, a sequential experiment analytical method was performed to determine the metal's relative mobility. According to the data, there is an average of 0.16 mg kg-1 of Cd in sediments. The BeniSuef water treatment plant and brick factory, the iron and steel factory of Helwan, the oil and detergent factory of Sohag, and the discharge of the cement factory in Samalut had the greatest concentration of Cd in their vicinity. According to the risk assessment code, there are four categories of Cd: residual (57.91%), acid-soluble (27.11%), reducible (11.84%), and oxidizable (3.14%). Bioavailable and mobile Cd levels in sediment and water were found in Beni Suef, Aswan; Helwan; Samalut; Sohag; and Helwan. Because the other metal is highly bioavailable, its concentration is not a risk factor at the Samalut station. Cd's toxicity and bioaccumulation make it an extra hazard to aquatic animals and human life. There should be a deterministic approach to monitoring Cd near industrial sources.

Impacts alum DWTPs sludge discharge and changes in flow regime of the Nile River on the quality of surface water and cultivated soils in Fayoum watershed, Egypt.

Discharge of Drinking Water Treatment Plants sludge directly on surface waters without any treatment is becoming an important issue in most countries around the world, behavior is not only affecting on the water quality, but also on soil and crops. This study investigated the effect of discharge of alum sludge and the variation in the level of the Nile water (flow regime) on water and soil qualities. The water samples were analyzed for physical, chemical and microbiological parameters. In winter (closure season), the mean values of EC, TDS, major ions, pH, DO and total algae count were higher than in summer. In summer (flooding season), it was noticed that the mean values of SiO2, metals, COD, BOD, TOC, nutrients and bacteriological parameters exceed winter season values. Moreover, the concentrations of Al, Fe, Mn were above WHO permissible limits and the concentrations of aggregate organic parameters exceed the FAO permissible limits in sites near the areas of sludge discharge. Most of water samples exceed the national guidelines. For soil, our findings showed that the concentrations of metals in soil samples collected from areas irrigated from canals receiving alum sludge are more (two-three times) than their concentrations from the pure sites. However, Pb concentration in the contaminated soil reaches ten times more than in the pure one. The management of sludge disposal becomes an urgent priority to save waterways, soil and crops from pollution. Finally, the variation in water flow during the winter closure period with reduction by ≈15 BCM is similar to the same reduction in the Nile flow when the Grand Ethiopian Renaissance Dam starts operation. This indicates that the long-term reduction in water flow due to the construction of this dam may cause serious environmental changes in the Nile River in Egypt.

Metal Fractionation in Surface Sediments of the Brahmaputra River and Implications for Their Mobilization.

The Brahmaputra River is the largest tropical river in India that flows along the Himalayan regions and it is the lifeline of millions of people. Metal fractionation in the Brahmaputra River's surface sediments and its correlation with turbidity are assessed in this study. The interaction between metal fractions and the overlying water is studied using multivariate statistical analyses. The strong positive correlation between NH4 of the overlying water and the exchangeable fractions in sediments signifies that the metals in the exchangeable fractions can be substituted by NH4. Subsequently, these metals can be released into the overlying water. The fluctuation in turbidity from 73 to 875 NTU indicates a large variation in the suspended matter concentration, and a higher concentration of suspended matter could provide attachment sites for pollutants such as metals. Significant variation in turbidity manifests a potentially high risk of pollution. In addition, the observation of local people along the Brahmaputra River turning its color to muddy indicates the need for continuous monitoring of water quality and an assessment of pollution is crucial. Although the Brahmaputra River's risk assessment code is at low risk, the exchangeable fractions of Ni and Zn are present at all sites. Thus, the Brahmaputra River requires early preventive measures and management strategies to control metal pollution. This study contributes to an understanding of the fluctuation of turbidity of a tropical river. We provide baseline data for policymakers, and the importance of further intensive studies on metal pollution in the Himalayan Rivers is highlighted.

Synthesis, Characterization of α-GaOOH Self-Assembly and Its Application in Removal of Perfluorinated Compounds.

This article discusses the hydrothermal synthesis of well-dispersed faceted α-GaOOH in the presence of sodium acetate by the self-assembly method. The synthesized α-GaOOH possesses a mixture of hexagonal and rectangular plates, cubic and diamond-like morphologies. The presence of ethanol as a co-solvent with water (1:1) facilitates scroll-like cylindrical morphology. The influences of sodium acetate concentration, hydrothermal temperatures, time and solvent on the formation of the above-mentioned morphologies were investigated. The synthesized α-GaOOH was characterized using X-Ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FE-SEM) and High-Resolution Transmission Electron Microscopy (HR-TEM), thermal analysis and nitrogen adsorption analysis. The XRD pattern confirmed the formation of orthorhombic α-GaOOH. The increase of the sodium acetate concentration from 0.031 mol/L to 0.250 mol/L facilitates the formation of more cubic and diamond-shaped particles than plate-like particles. The formation of faceted α-GaOOH is slow at 150 degrees C, and a further increase in hydrothermal temperature from 175 degrees C to 225 degrees C had no appreciable effect. Similarly, an increase in hydrothermal time from 5 h to 20 h at 200 degrees C facilitates hexagonal to cubic shaped plates. The solution pH strongly influenced the aspect ratio of the nanoplates. Hydrothermal temperature and time had no appreciable effect from 175 degrees C to 225 degrees C. The removal perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) using the synthesized α-GaOOH was studied. A plausible mechanism for the formation of nanoplates is proposed.