1.
Chem Commun (Camb)
; 57(86): 11326-11329, 2021 Oct 28.
Article
in English
| MEDLINE
| ID: mdl-34636827
ABSTRACT
A new topotactic oxidation was developed using the solid-state oxidant Zr-doped CeO2. For the anti-ThCr2Si2 type Y2O2Bi, which became superconducting via oxygen intercalation during solid-state oxidation at 1000 °C, the topotactic oxidation enabled not only the oxygen intercalation at a much lower temperature of 200 °C, hampering the segregation of impurity phases, but also the highest superconducting transition temperature for Y2O2Bi.