Sustainable conversion of biomass to rationally designed lithium-ion battery graphite.

The carbon net negative conversion of bio-char, the low value byproduct of pyrolysis bio-oil production from biomass, to high value, very high purity, highly crystalline flake graphite agglomerates with rationally designed shape and size tailored for lithium-ion battery energy storage material is reported. The process is highly efficient, 0.41 g/Wh; the energy content of its co-product of the process, bio-oil, exceeds that needed to power the process. It is shown that the shape of the starting material is retained during the transformation, allowing the ultimate morphology of the graphite agglomerates to be engineered from relatively malleable biomass. In contrast to commercial graphite production, the process can be performed at small scale with low equipment costs, enabling individual research laboratories to produce Li-ion grade graphite with customizable shape, size and porosity for Si/graphite composite and other graphite involved anodes. The mechanism of the graphitization of bio-char, a "non-graphitizable" carbon, is explored, suggesting the molten metal catalyst is absorbed into the pore structure, transported through and transforming the largely immobile biochar. Finally, the transformation of biomass to rationally designed graphite morphologies with Li-ion anode performance that closely mimic commercial shaped graphite is demonstrated.

Ink synthesis and inkjet printing of electrostatically stabilized multilayer graphene nanoshells.

HYPOTHESIS: Most functional inkjet inks are sterically stabilized nanoparticle dispersions that require a post-printing-process to remove stabilizing materials and gain functionality. This post-process limits material selection and increases fabrication time and complexity for printed devices. By optimizing the electrostatic stability of a carbon nanomaterial dispersed in water or ethylene glycol via pH adjustment, a stable and printable ink should be attainable without a steric stabilizing material and hence the post-process may be avoided. EXPERIMENTS: The electrostatic stability of multilayer graphene nanoshells (MGNS)-an inexpensive and net carbon-negative nanomaterial-dispersed in water and ethylene glycol was studied by measuring zeta potential as a function of pH and modeling energetic potentials between particles. Requirements for electrical percolation of printed MGNS were analyzed and corroborated with electrical measurements. FINDINGS: Electrostatic stability improved with increased zeta potential caused by an increased pH. Ionic strength also increased with pH, causing strong destabilization. By increasing zeta potential while minimizing ionic strength, the maximum solid-loading of MGNS in DI water and ethylene glycol was increased up to 20%. For the MGNS solid-loading achieved here, electrical percolation occurs with 20-30 consecutively printed layers producing a resistivity of 30 Ω-cm. The inexpensive, environmentally-friendly MGNS are a promising material for printed, flexible electronics.