Effect of Cyrtostachys renda Fiber Loading on the Mechanical, Morphology, and Flammability Properties of Multi-Walled Carbon Nanotubes/Phenolic Bio-Composites.

This research focuses on evaluating the effect of Cyrtostachys renda (CR) fiber and the impact of adding multi-walled carbon nanotubes (MWCNT) on the morphological, physical, mechanical, and flammability properties of phenolic composites. MWCNT were supplemented with phenolic resin through a dry dispersion ball milling method. Composites were fabricated by incorporating CR fiber in 0.5 wt.% MWCNT-phenolic matrix by hot pressing. Nevertheless, the void content, higher water absorption, and thickness swelling increased with fiber loading to the MWCNT/phenolic composites. The presence of MWCNT in phenolic enhanced the tensile, flexural, and impact strength by as much as 18%, 8%, and 8%, respectively, compared to pristine phenolic. The addition of CR fiber, however, strengthened MWCNT-phenolic composites, improving the tensile, flexural, and impact strength by as much as 16%, 16%, and 266%, respectively, for 50 wt.% loading of CR fiber. The CR fiber may adhere properly to the matrix, indicating that there is a strong interface between fiber and MWCNT-phenolic resin. UL-94 horizontal and limiting oxygen index (LOI) results indicated that all composite materials are in the category of self-extinguishing. Based on the technique for order preference by similarity to the ideal solution (TOPSIS) technique, 50 wt.% CR fiber-reinforced MWCNT-phenolic composite was chosen as the optimal composite for mechanical and flammability properties. This bio-based eco-friendly composite has the potential to be used as an aircraft interior component.

Physical, Mechanical, and Morphological Properties of Hybrid Cyrtostachys renda/Kenaf Fiber Reinforced with Multi-Walled Carbon Nanotubes (MWCNT)-Phenolic Composites.

Adequate awareness of sustainable materials and eco-legislation have inspired researchers to identify alternative sustainable and green composites for synthetic fiber-reinforced polymer composites in the automotive and aircraft industries. This research focused on investigating the physical, mechanical, and morphological properties of different hybrid Cyrtostachys renda (CR)/kenaf fiber (K) (10C:0K, 7C:3K, 5C:5K, 3C:7K, 0C:10K) reinforced with 0.5 wt% MWCNT-phenolic composites. We incorporated 0.5 wt% of MWCNT into phenolic resin (powder) using a ball milling process for 25 h to achieve homogeneous distribution. The results revealed that CR fiber composites showed higher voids content (12.23%) than pure kenaf fiber composites (6.57%). CR fiber phenolic composite was more stable to the swelling tendency, resulting in the lowest percentage of swelling rate (4.11%) compared to kenaf composite (5.29%). The addition of kenaf fiber into CR composites had improved the tensile, flexural, and impact properties. The highest tensile and flexural properties were found for weight fraction of CR and kenaf fiber at 5C:5K (47.96 MPa) and 3C:7K (90.89 MPa) composites, respectively. In contrast, the highest impact properties were obtained for 0C:10K composites (9.56 kJ/m2). Based on the FE-SEM image, the CR fiber lumen was larger in comparison to kenaf fiber. The lumen of CR fiber was attributed to higher void and water absorption, lower mechanical properties compared to kenaf fiber. 5C:5K composite was selected as an optimal hybrid composite, based on the TOPSIS method. This hybrid composite can be used as an interior component (non-load-bearing structures) in the aviation and automotive sectors.

Effect of Nanofiller Content on Dynamic Mechanical and Thermal Properties of Multi-Walled Carbon Nanotube and Montmorillonite Nanoclay Filler Hybrid Shape Memory Epoxy Composites.

The aim of the present study has been to evaluate the effect of hybridization of montmorillonite (MMT) and multi-walled carbon nanotubes (MWCNT) on the thermal and viscoelastic properties of shape memory epoxy polymer (SMEP) nanocomposites. In this study, ultra-sonication was utilized to disperse 1%, 3%, and 5% MMT in combination with 0.5%, 1%, and 1.5% MWCNT into the epoxy system. The fabricated SMEP hybrid nanocomposites were characterized via differential scanning calorimetry, dynamic mechanical analysis, and thermogravimetric analysis. The storage modulus (E'), loss modulus (E"), tan δ, decomposition temperature, and decomposition rate, varied upon the addition of the fillers. Tan δ indicated a reduction of glass transition temperature (Tg) for all the hybrid SMEP nanocomposites. 3% MMT/1% MWCNT displayed best overall performance compared to other hybrid filler concentrations and indicated a better mechanical property compared to neat SMEP. These findings open a way to develop novel high-performance composites for various potential applications, such as morphing structures and actuators, as well as biomedical devices.