Pyrolysis and catalytic pyrolysis as a recycling method of waste CDs originating from polycarbonate and HIPS.

Pyrolysis appears to be a promising recycling process since it could convert the disposed polymers to hydrocarbon based fuels or various useful chemicals. In the current study, two model polymers found in WEEEs, namely polycarbonate (PC) and high impact polystyrene (HIPS) and their counterparts found in waste commercial Compact Discs (CDs) were pyrolysed in a bench scale reactor. Both, thermal pyrolysis and pyrolysis in the presence of two catalytic materials (basic MgO and acidic ZSM-5 zeolite) was performed for all four types of polymers. Results have shown significant recovery of the monomers and valuable chemicals (phenols in the case of PC and aromatic hydrocarbons in the case of HIPS), while catalysts seem to decrease the selectivity towards the monomers and enhance the selectivity towards other desirable compounds.

Tensile bond characteristics between composite resin and resin-modified glass-ionomer restoratives used in the open-sandwich technique.

BACKGROUND: The clinical success of large class II resin-modified glass-ionomer cement/composite resin (RMGIC/CR) 'open-sandwich' restorations in permanent or primary molars may be influenced by certain bonding parameters. AIM: To examine in vitro the effect of placing/curing mode on the RMGIC/CR bond strength. DESIGN: Two restoratives, a CR (Z250), a RMGIC (Vitremer) and a bonding agent (Adper Single Bond 2), all of 3M ESPE, were used for preparing five groups of seven specimen sticks each. The bond between the two restorative materials at the stick centre was created in the three test groups by: (A) 1-step placing RMGIC in contact with CR, then photocuring; (B) 2-step RMGIC placing/curing, then CR placement/curing; (C) 3-step RMGIC placing/curing, bonding agent placing/curing, CR placing/curing. Control groups consisted of sticks made of CR alone (D, positive) and RMGIC alone (E, negative). The specimens were subjected to tensile stress measurements in an Instron dynamometer and examined by scanning electron microscope for type of failure. STATISTICS: Tensile bond strength, tensile strain and elastic modulus differences were examined with one-way ANOVA and Tukey test. RESULTS: Among experimental groups, Group C exhibited significantly higher tensile strength (MPa) means (A = 12.11 ± 4.72, B = 15.69 ± 5.18, C = 19.08 ± 4.05) and significantly higher tensile strain (%) means (A = 0.50 ± 0.11, B = 0.64 ± 0.19, C = 0.98 ± 0.24), compared to Group A, at p = 0.05. Group D had significantly higher tensile strength and strain than all other groups. No statistically significant differences were observed in the elastic modulus. The use of bonding agent (Group C) resulted in absence of adhesive failures as seen by SEM. CONCLUSION: The use of bonding agent improved the CR/RMGIC bond by tensile strength and strain tests.

Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP).

The recycling of either model polymers or waste products based on low-density polyethylene (LDPE), high-density polyethylene (HDPE) or polypropylene (PP) is examined using the dissolution/reprecipitation method, as well as pyrolysis. In the first technique, different solvents/non-solvents were examined at different weight percent amounts and temperatures using as raw material both model polymers and commercial products (packaging film, bags, pipes, food-retail outlets). The recovery of polymer in every case was greater than 90%. FT-IR spectra and tensile mechanical properties of the samples before and after recycling were measured. Furthermore, catalytic pyrolysis was carried out in a laboratory fixed bed reactor with an FCC catalyst using again model polymers and waste products as raw materials. Analysis of the derived gases and oils showed that pyrolysis gave a mainly aliphatic composition consisting of a series of hydrocarbons (alkanes and alkenes), with a great potential to be recycled back into the petrochemical industry as a feedstock for the production of new plastics or refined fuels.