ABSTRACT
The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant inter-molecular inter-actions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944â (1):0.056â (1).
ABSTRACT
The title compound, C(17)H(14)Cl(4)N(2)O(2), is generated by crystallographic twofold symmetry. The two benzene rings are inclined to one another by 80.17â (10)°. There are two intra-molecular O-Hâ¯N hydrogen bonds, which make S(6) ring motifs. In the crystal, mol-ecules are linked by C-Hâ¯O and weak C-Hâ¯Cl inter-actions, forming a three-dimensional network.
ABSTRACT
The asymmetric unit of the title compound, C(16)H(12)Br(4)N(2)O(2), comprises half of a potential tetra-dentate Schiff base ligand. The whole mol-ecule is generated by an inversion center located in the middle of the C-C bond of the ethyl-ene segment. There are intra-molecular O-Hâ¯N hydrogen bonds making S(6) ring motifs. In the crystal, no significant inter-molecular inter-actions are observed.
ABSTRACT
In the title compound, C(17)H(14)I(4)N(2)O(2), there are two intra-molecular O-Hâ¯N hydrogen bonds, which make S(6) ring motifs. In the crystal, there are no significant inter-molecular inter-actions present.
ABSTRACT
The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex mol-ecule of formula [Cu(2)(C(18)H(14)Br(4)N(2)O(2))(2)](n). One of the Cu(II) ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu-O bond [2.885â (4)â Å] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. π-π stacking inter-actions [centroid-centroid distance = 3.783â (4)â Å] and short inter-chain Brâ¯Br inter-actions [3.6142â (12)-3.6797â (12)â Å] are observed.
ABSTRACT
In the title Schiff base complex, [Ni(C(18)H(14)Cl(4)N(2)O(2))(C(3)H(7)NO)(2)], the geometry around the Ni(II) atom is distorted octa-hedral. It is coordinated by the N(2)O(2) donor atoms of the tetra-dentate Schiff base ligand and the O atoms of two dimethyl-formamide mol-ecules, which are cis to one another. The benzene rings are almost normal to each other [dihedral angle = 88.60â (14)°]. The various intra-molecular C-Hâ¯O hydrogen bonds make S(5) and S(6) ring motifs. In the crystal, mol-ecules are linked by pairs of weak C-Hâ¯Cl inter-actions, forming inversion dimers.
ABSTRACT
The asymmetric unit of the title compound, [Cu(2)(C(18)H(14)Cl(4)N(2)O(2))(2)](n), contains two independent Cu(II) ions which are bridged by a pair of 4,4',6,6'-tetra-chloro-2,2'-[butane-1,4-diylbis(nitrilo-methanylyl-idene)]diphenolate ligands, forming a dinuclear unit. One of the Cu(II) ions is coordinated in a distorted square-planar environment and the other is coordinated in a distorted square-pyramidal environment. The long apical Cu-O bond of the square-pyramidal coordinated Cu(II) ion is formed by a symmetry-related O atom, creating a one-dimensional polymer along [010]. In addition, short inter-molecular Clâ¯Cl distances [3.444â (2)â Å] and weak π-π inter-actions [centroid-centroid distances = 3.736â (2)-3.875â (3)â Å] are observed. The crystal studied was an inversion twin with a refined twin component ratio of 0.60â (1):0.40â (1).
ABSTRACT
The asymmetric unit of the title compound, C(16)H(12)Cl(4)N(2)O(2), comprises half of a potentially tetra-dentate Schiff base ligand, located about a twofold rotation axis which bis-ects the central C-C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic form. There are two intra-molecular N-Hâ¯O hydrogen bonds making S(6) ring motifs. In the crystal, mol-ecules are linked by C-Hâ¯O hydrogen bonds, forming two-dimensional frameworks which lie parallel to (100). There are also short Clâ¯Cl [3.4395â (9)â Å] contacts present.
ABSTRACT
The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetra-dentate Schiff base ligand. It is located about a twofold rotation axis that bis-ects the central C-C bond of the butane-1,4-diamine group. There are two intra-molecular O-Hâ¯N hydrogen bonds making S(6) ring motifs. In the crystal, mol-ecules are linked by pairs of weak C-Hâ¯Cl inter-actions, forming inversion dimers, which are further connected by C-Hâ¯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001).
ABSTRACT
The asymmetric unit of the title compound, C(18)H(16)Br(4)N(2)O(2), comprises half the molecule, which is located adjacent to an inversion centre at the mid-point of the central C-C bond of the butane-1,4-diamine segment. There are two intra-molecular O-Hâ¯N hydrogen bonds making S(6) ring motifs. In the crystal, mol-ecules are linked by pairs of weak C-Hâ¯Br inter-actions into chains along [101], which include R(2) (2)(8) ring motifs. These chains are further linked by C-Hâ¯O hydrogen bonds, forming a three-dimensional network.
ABSTRACT
In the title mol-ecule, C(9)H(11)N(3)O(2)S, an intra-molecular O-Hâ¯N hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked via pairs of N-Hâ¯S inter-actions, forming inversion dimers with R(2) (2)(8) ring motifs. These dimers are further linked via N-Hâ¯S and N-Hâ¯O hydrogen bonds, forming a two-dimensional network lying parallel to (100). The crystal structure is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance = 3.7972â (9)â Å].
ABSTRACT
The title compound, C(10)H(13)N(3)O(2)S, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In the crystal, the A and B mol-ecules are linked via pairs of N-Hâ¯O and O-Hâ¯S hydrogen bonds, forming dimers with R(2) (2)(14) and R(2) (2)(6) ring motifs. These dimers are linked via a pair of N-Hâ¯S hydrogen bonds with an R(2) (2)(8) ring motif, forming chains propagating along the c-axis direction. The crystal was refined as an inversion twin with a final BASF ratio of 0.54â (11):0.46â (11).