Evaluation of soil-gas radon concentrations from different geological units with varying strata in a crystalline basement complex of southwestern Nigeria.

The aim of this study is to determine the variation of soil-gas radon concentrations from different rock formations in Ogbomoso, southwestern Nigeria. The radon concentrations at different five geological domains in Ogbomoso are determined with respect to depth. The measurements varied from the surface (0 cm) to 100 cm depth, with an interval of 20 cm. At all the geological domains (Porphyroclastic, Granite, Quartzite, Migmatite and Banded gneiss), radon has its minimum emission over migmatite at 0 cm, while its maximum emissions occured over granite and banded gneiss at 80 cm. The overall soil-gas radon concentrations in Ogbomoso varied from 0.06 to 26.5 kBq/m3, which is within the natural limit of 0.4 to 40 kBq/m3 based on the International Commission on Radiological Protection's recommendation. An F-ratio of 6.989 and a p-value of 0.001 were obtained for the first inferential hypothesis, while an F-ratio of 2.489 and a p-value of 0.076 were obtained for the second inferential hypothesis using ANOVA test. The post hoc (using Tukey HSD and Duncan) tests revealed that at 60 + cm, depth controls the level of radon concentrations being emanated from the subsurface. The pollution index in Ogbomoso is of level 1 at 80 cm and level 0 (safe limit) at other depths. In conclusion, the soil-gas radon emission depends on the local geology and lithological sequences (depths). Cracks that could act as passage for indoor radon at the floors of the buildings around the polluted zones should be avoided in order to have a sustainable city.

Health risk indices and zooplankton-based assessment of a tropical rainforest river contaminated with iron, lead, cadmium, and chromium.

Oil exploration's devastation on health and the environment may far outweigh its economic benefits. An oil spill occurred at Egbokodo River in Delta State, Nigeria, thereby polluting the land and water bodies. The study was therefore aimed at evaluating the impacts of iron, lead, cadmium, and chromium on the zooplankton community structure of Egbokodo River and the potential health risks. Zooplankton and surface water samples were collected to investigate the concentrations of trace metals and zooplankton abundance. The associated carcinogenic and non-carcinogenic effects of the metals in the water were analyzed. Trace metal concentrations in the surface water were determined using atomic absorption spectroscopy (Philips model PU 9100) and zooplankton samples were collected using a hydrobios plankton net (mesh size 25 µm). Total petroleum hydrocarbons (TPH) and oil and grease (OG) were determined using Agilent 7890B gas chromatography coupled to flame ionization detector (GC-FID) and volumetric analysis respectively. The trend of the abundance of zooplanktons cross the river was 18 individuals (Station A) < 100 individuals (Station B) < 155 individuals (Station C). Cyclopoida proved to be the most resilient to the impacts of the oil spill. On a taxa basis, the order of abundance among Calanoida, Cyclopoida, Cladoceran, and Harpacticoida was Station C > Station B > Station A, except in Amphipoda where Station B > Station C > Station A was observed. Iron and lead posed significant carcinogenic risks that are liable to be inflicted by the ingestion of the water. The cumulative non-carcinogenic health risk in the male was the only significant (> 1) among the age groups. Total petroleum hydrocarbons (TPH), oil and grease (OG), iron, and lead had notable impacts on the general abundance of zooplankton in the aquatic habitat. The dominance of the Cyclopoida in the river buttressed the impact of the oil spill which warrants a prompt remediation measure. The pollution had notable ecological impacts on the zooplankton community structure of the aquatic habitat. The adults in the nearby human populations are liable to elicit carcinogenic health challenges associated with lead and iron ingestion. The males are at risk of non-carcinogenic illnesses which are associated with the combined toxicity effects of all the metals. The study suggests that the pollution in Egbokodo River was validated by the dominance of the Cyclopoida in the aquatic habitat. The study confers bioindicator reputation on the Cyclopoida for future biomonitoring studies.

Principal Components and Hierarchical Cluster Analyses of Trace Metals and Total Hydrocarbons in Gills, Intestines and Muscles of Clarias gariepinus (Burchell, 1822).

The aim of the study was to comparatively analyze the interrelationships among iron (Fe), manganese (Mn), zinc (Zn), copper (Cu), lead (Pb), cadmium (Cd), chromium (Cr) and total hydrocarbons (THCs) in the gills, intestines and muscles of Clarias gariepinus collected from Osse River, Nigeria, between the periods of April, 2013 to September, 2014. The trace metals in the fish tissues were analyzed using Atomic Absorption Spectrophotometer (AAS, Philips model PU 9100), while total hydrocarbons were analyzed using High Performance Liquid Chromatograph (HPLC,Prominence Dual brand from HGE) equipped with a detector Shimadzu UV-Visible (UV-Vis Prominence SPD 20 A). The concentrations of trace metals and THCs in the tissues were subjected to principal component analysis (PCA), in conjunction with hierarchical cluster analysis (HCA), backed up by correlation analysis (CA). In the most prioritized component among the hierarchies of contaminants, characterized as principal component 1, results of communality extractions and rotated component matrices revealed the order of contaminants was Mn > Cu > Zn > Fe > Cr in the intestines, Cr > Cu > THCs > Mn > Fe in the muscle, while Pb > Cr > Fe > Mn was the order in the gills of the fish. Iron inhibited accumulation of the other trace metals in the gills, where its threshold of essentiality was maximal. Noteworthy is the fact that Mn and Cu were the most active components in the muscle and concurrently of excess concentrations in the tissue, which is the major edible part of fish, and constitutes its main body weight, hence holds its nutritional and economic values. High level of variability which occurred in the toxicant profile across the tissues of C. gariepinus is a function of uptake route, varied organ functions and specificity of tissue permeability of the compared organs. The study demonstrated variability in organ accumulation capacity and toxicant's competitiveness irrespective of bioavailability. The study provides data useful for future ecotoxicological studies and safety of consumers of the fish.

Natural radionuclides and radiological risk assessment of granite mining field in Asa, North-central Nigeria.

In this study, a well calibrated Super-Spec (RS-125) gamma spectrometer was used to measure the activity concentrations of 40K, 238U, 232Th and gamma doses rate at 1 m above the ground level over a granite mining field in Asa, Kwara State, North-central Nigeria. Measurements were carried out in 50 randomly selected sample points. The overall mean activity concentrations of 40K, 238U, 232Th and gamma dose are 570.91, 42.86, 18.15 Bqkg-1 , and 60.11 nGyh-1 respectively. The results of the activity concentrations were used to estimate the corresponding radiation hazard parameters to assess the suitability of the granite for building and construction purposes. The data in this study could serve as the baseline radiological data of the region for future references. •Activity concentrations of 40K,238U,232Th and gamma doses were measured over a granite mining field in Asa.•The total mean activity concentrations of the radioisotopes and gamma dose are 570.91, 42.86, 18.15 Bqkg-1 , and 60.11 nGyh-1 respectively.•The radiological hazards are higher than the recommended permissible limits.

Evaluation of 0 ≤ M ≤ 8 earthquake data sets in African - Asian region during 1966-2015.

This article evaluates the occurrence of 0 [Formula: see text]M[Formula: see text] 8 earthquake data sets for the period of 50 years (that is, January 1, 1966 to December 31, 2015) in African and Western Asia region. It is bounded by latitude 40° S to 40° N and longitude 30° W to 60° E with the focal depth of 0-700 km. Seventy seven thousand, six hundred and ninety-six data points were presented for the analysis. The data used were extracted from earthquake catalog of Advanced National Seismic system via http://quake.geo.berkeley.edu/cnss/, an official website of the Northern California Earthquake Data Centre, USA. Each datum comprised the earthquake occurrence date, time of the earthquake occurrence, epicenter's coordinates, focal depth and magnitude. The Gutenberg-Richter's relationship being the longest observed empirical relationship in seismology, analysis of variance and time series were used to analyze the seismicity of the study area. Annual distributions of earthquake occurrence based on magnitude variations with the limit 0 [Formula: see text]M[Formula: see text] 8 were presented. The two constants a and b in the Gutenberg-Richter's equation, magnitude of completeness (MC) adjusted R-Square and F-value for the period of 1966-1975, 1976-1985, 1986-1995, 1996-2005, 2006-2015, and the entire period of investigation ranging from 1966 to 2015 were determined so as to investigate the variations of these parameters on earthquake occurrence over time. The histograms of earthquake occurrence against magnitude of earthquakes for the selected years (1966-1975, 1976-1985, 1986-1995, 1996-2005, 2006-2015, and 1966-2015), and the decadal frequency distributions of earthquake occurrence were also plotted. The focal depth occurrence for each magnitude bins (0-0.9, 1-1.9, 2-2.9, 3-3.9, 4-4.9, 5-5.9, 6-6.9, 7-7.9, 8-8.9) were grouped into shallow, intermediate, and deep depths ranging from 0 to 70, 71 to 300, and 301 to 700 km as being used in seismology. The neural network analysis was also applied to the magnitude of the earthquake. The network uses a time series magnitude data as input with the output being the magnitude of the following day. If the nature of the earthquakes time series is stochastic, modeling and prediction is possible. The earthquake data sets presented in this article can further be adopted in the study of seismicity pattern, b-value using series of models, earthquake prediction and variations of earthquake parameters on African and/or Arabian plates. When this approach is integrated with other technique(s), it can provide insights to stability of African lithospehric plates especially the coastal region of Africa.