ABSTRACT
Plastic has become an essential ingredient in social life, especially in its function as food packaging. An increase in plastic consumption can have a big impact, especially on environmental issues, because of the plastic waste produced. Substituting petroleum-based plastic with bionanocomposites can be done to reduce the impact of environmental issues caused by plastic waste. The purpose of this study is to produce nanoparticle-incorporated bioplastics, which can be applied as alternative food packaging, especially as petroleum-based plastic substitutes, and as food packaging that has added value in the form of antimicrobial properties. In addition, nanoparticles are also intended to improve the characteristics of bioplastics such as improving mechanical properties and film permeability as well as increasing the barrier properties of bioplastics against ultraviolet rays that can damage packaged food. Bionanocomposites with modified forms were investigated by various characterization such as Fourier transform infrared (FTIR), mechanical property testing of bioplastics as well as analysis of water vapor permeability (WVP), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), UV-visible spectrophotometry (UV-vis), and antimicrobial testing. Visible improvement of mechanical and UV barrier properties was seen in bionanocomposites with the addition of cerium nanoparticles. Furthermore, we have also demonstrated the antibacterial activity properties of nanoparticle-loaded bionanocomposites, which can add value to their use as food packaging. These results indicate that carrageenan-based bionanocomposites have a high potential for positive application in food packaging to ensure food safety and extend the shelf life of packaged foods.
ABSTRACT
TiO2 particles with a specific morphology are essential for their accessibility and photoactivity. The present study shows that NH4OH-based alkaline-hydrothermal treatment affects the transformation of their particle morphology. We investigated the effect of NH4OH by varying the synthesis route. We observed that the TiO2 particles with an open channel pore structure only resulted in the alkaline-hydrothermally treated and calcined samples. Based on Raman and XRD analyses, we figured out the titanate layers as an intermediate phase resulting from the alkaline-hydrothermal treatment of the amorphous particles. The hydrothermal treatment changed the particle surface morphology into a lamellar structure with a high specific surface area. These are the anatase precursors with {200} planes that transform into the anatase phase after calcination. The calcination followed by alkaline-hydrothermal treatment converted the crystallinity without significantly changing their morphology. We found that the morphology of TiO2 particles can be modified via hydrothermal treatment using NH4OH as long as the particles remain uncrystallized. We suggested the modification of particle morphology through the swelling and phase segregation process by alkaline-hydrothermal treatment. All final products have been used for the photodegradation of rhodamine B. S-HT-500 and A-HT-500 show the best photocatalytic activity with their rate constants (k) of 47.9 and 30.9 × 10-2 min-1, and their surface area-normalized rate constants (ksa) of 6.5 and 2.6 × 10-3 L m-2 min-1, respectively, and have a photocatalytic efficiency of 90.93% and 67.78%, respectively, after 10 minutes of UV irradiation. This activity is approximately 3.5 times and 1.5 times higher than that of Degussa P25; 30 times and 20 times higher than that without a photocatalyst.
ABSTRACT
The thermodynamic picture describing the formation mechanism of bicontinuous concentric lamellar (bcl) nanostructured silica particles, bcl silica, was investigated thoroughly. A series of classical kinetics of bcl silica by varying the synthesis time were employed to observe the morphological evolution of bcl silica. The formation mechanism of bcl silica is proposed as the hydrolysis and condensation reactions in the reverse micelle, followed by the phase segregation process. The images of the whole part and the cross-section of bcl silica reveal that bcl silica can be obtained just 30 min after the synthesis starts. The particle morphology evolves from bicontinuous lamellar (bl) morphology, with the absence of the dense part in the center of the particle, to bicontinuous concentric lamellar (bcl) morphology. The theoretical part of this study is focused on the phase segregation process of the mixture. This process is divided thermodynamically into several reversible processes based on the reduced Helmholtz free energy state function. The type of the lamellar orientation (i.e., parallel or perpendicular orientation) changed as the stacked lamellae changed in thickness and was followed by the decrease in the free energy. It was merely shown that the segregation of the thin slab of the lamellar polysiloxane stack favors the perpendicular orientation. In contrast, the thick slab of the lamellar polysiloxane stack yields a complex lamellar structure consisting of perpendicular and parallel orientations. A lamellar polymer confined between two planar substrates can experience a topological transformation into a sphere due to an unfavorable environment, i.e., high surface tension. After the topological transformation, lamellae with a perpendicular orientation form bicontinuous lamellae, whereas the complex lamellar structure transforms into a bicontinuous concentric lamellar morphology.
