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1.
J Prosthet Dent ; 121(1): 129-134, 2019 Jan.
Article in English | MEDLINE | ID: mdl-29961625

ABSTRACT

STATEMENT OF PROBLEM: The gradual loss of retention and the need for periodic replacement of attachment-system components are the most frequent complications in implant-supported overdentures. PURPOSE: The purpose of this in vitro study was to develop a new attachment system for overdentures with polymeric materials and compare its retention and deformation with a conventional O-ring attachment system. MATERIAL AND METHODS: A matrix with 2 mini-implants with ball abutments was used to simulate the mandibular border during a fatigue resistance test. A total of 60 polyacetal (n=20), polytetrafluoroethylene (n=20), and conventional O-ring (n=20) attachments were captured in pairs with acrylic resin and subjected to 3625 insertion and removal cycles, simulating 30 months of overdenture use. The internal and external deformations of the attachments were assessed using an optical stereomicroscope. One-way ANOVA and the Tukey honestly significant difference tests were used for statistical evaluation (α=.05). RESULTS: The polyacetal attachment system showed the highest retention (P<.001), followed by the O-ring and polytetrafluoroethylene attachments. The O-ring attachments exhibited the lowest deformation (P<.001), and the polyacetal attachments had the highest internal deformation (P<.001). CONCLUSIONS: The newly developed polyacetal attachment model increased the retention of mini-implant-retained overdentures, and despite the deformation experienced, the retention period appears to be better than that of conventional systems.


Subject(s)
Dental Implants , Dental Prosthesis, Implant-Supported/instrumentation , Denture Precision Attachment , Denture Retention , Denture, Overlay , Acetals/chemistry , Dental Abutments , Dental Prosthesis, Implant-Supported/methods , Dental Stress Analysis , Humans , In Vitro Techniques , Mandible , Materials Testing , Polymers/chemistry , Polytetrafluoroethylene/chemistry
2.
Article in English | MEDLINE | ID: mdl-20063227

ABSTRACT

Recycling of plastics for food-contact packaging is an important issue and research into meaningful and cost-effective solutions is in progress. In this paper, the use of sub-critical water was evaluated as an alternative way of purifying poly(ethylene terephthalate) (PET) flakes for direct food contact applications. The effects of temperature, pressure and flow rate were assessed on the extraction efficiency of two of the most challenging classes of contaminants (toluene and benzophenone) from PET by sub-critical water using a first-order fractional experimental design. Extraction yield was quantified using GC/FID. The most important parameter was flow rate, indicating that the decrease in sub-critical water polarity with temperature was insufficient to eliminate partition effects. Temperature was also important, but only for the optimization of toluene extraction. These results may be explained by the poor solubility of higher molar mass compounds in sub-critical water compared to lower molar mass compounds under the same conditions, and the small decrease in dielectric constant with temperature under the experimental conditions evaluated. As cleaning efficiency is low and PET is very susceptible to hydrolysis, which limits the use of higher temperatures vis-à-vis physical recycling, the proposed extraction is unsuitable for a standalone super-clean process but may be a step in the process.


Subject(s)
Conservation of Natural Resources/methods , Food Contamination/prevention & control , Food Packaging/instrumentation , Polyethylene Terephthalates/chemistry , Water/chemistry , Benzophenones/isolation & purification , Chemical Phenomena , Chromatography, Gas/methods , Food Contamination/analysis , Polyethylene Terephthalates/analysis , Solubility , Temperature , Toluene/isolation & purification
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