Zeolitic imidazolate framework (ZIF-8) modified cellulose acetate NF membranes for potential water treatment application.

In this study, cellulose acetate (CA)-based nanofiltration membranes, modified with zeolitic imidazole framework-8 (ZIF-8) particles, were prepared with various ZIF-8 contents (0, 0.1, 0.25, 0.5, 1 and 2 wt%), to obtain membranes with improved flux and filtration performance by combining advantages of CA polymer and ZIF-8 metal-organic frameworks. Removal efficiency studies were carried out with bovine serum albumin and two different dyes, along with antifouling performance evaluation. Results of experiments disclosed that as the ZIF-8 ratio increased, the contact angle values decreased. With ZIF-8 addition, the pure water flux of the membranes increased. Besides, the flux recovery ratio value was approximately 85 % for the bare CA membrane, while it increased to above 90 % by blending ZIF-8. Also, in all ZIF-8 doped membranes, a fouling decrease was observed. Importantly, it was observed that the dye removal efficiency increased with the addition of ZIF-8 particles from 95.2 to 97.7 % for Reactive Black 5 dye.

Nanomaterials in membrane bioreactors: Recent progresses, challenges, and potentials.

The use of nanomaterials (NMs) in the fabrication and modification of membranes as well as the coupling of nanomaterial-based processes with membrane processes have been attracted many researchers today. The NMs due to a wide range of types, different chemistry, the possibility of various kinds of functionality, different properties like antibacterial activity, hydrophilicity, and large surface area were applied to enhance the membrane properties. In the membrane bioreactors (MBRs) as a highly successful process of membrane technology in wastewater treatment, the NMs have been applied for improving the efficiency of MBR process. This review assessed the application of NMs both as the modifiers of membrane and as the effective part of hybrid techniques with MBR system for wastewater treatment. The efficiency of NMs blended membranes in the MBR process has been reviewed in terms of antifouling and antibacterial improvement and removal performance of the pollutants. Novel kinds of NMs were recognized and discussed based on their properties and advantages. The NMs-based photocatalytic and electrochemical processes integrated with MBR were reviewed with their benefits and drawbacks. In addition, the effect of the presence of mobilized NPs in the sludge on MBR performance was surveyed. As a result of this review, it can be concluded that nanomaterials generally improve MBR performance. The high flux and antifouling properties can be obtained by adding nanomaterials with hydrophilic and antibacterial properties to the membrane, and further studies are required for photocatalytic NMs applications. In addition, this review shows that the low amounts of NMs in the membrane structure could have an effective influence on the MBR process. Besides, since many studies in the literature are carried out at the laboratory scale, it is thought that pilot and real-scale studies should be carried out to obtain more reliable data.

Ceramic membrane overview and applications in textile industry: a review.

The importance of water recovery and reuse is increasing day by day. Therefore, the use of advanced technologies is applied for the treatment and recovery of textile wastewater. The fact that ceramic membranes are resistant to the challenging characteristics of textile wastewater makes the use of ceramic membranes useful. Within the scope of this review, general information about the textile industry and treatment techniques are mentioned, as well as the properties of ceramic membranes and textile wastewater treatment. In the literature review made in this study, recent studies on the production of ceramic membranes and laboratory applications have been compiled. However, it has been observed that although the real-scale studies are relatively higher in industries such as the food and petrochemical industry, it is rather limited in the textile industry.

Nanofiltration membranes for salt and dye filtration: effect of membrane properties on performances.

In this study, commercial nanofiltration membranes (Toray, NF 270, Desal 5 L) were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, optical profilometry, contact angle, mechanical strength and zeta potential measurements. Filtration performance tests were conducted with distilled water, MgSO4 solution and synthetic dye solutions, respectively. Among three commercial membranes, the Toray membrane was thought to be better choice. Additional experiments were carried out for a more detailed characterization of the selected membrane. Therefore, firstly, flux and removal efficiency was monitored by using dye solutions at different pH values, and then experiments were carried out to observe the effect of different temperatures. Also, another filtration test with NaCl solution was performed for the Toray membrane. As the main purpose of this study, we aimed to establish a significant correlation between the structural properties of membranes and their performances. In light of the results obtained, it was observed that the contact angle, mechanical strength and surface roughness values of the membrane significantly affected the membrane performance. It was concluded that the most important parameter in dye removal was the zeta potential. As a result of this work, a data set of commercial membranes was created and is available to all membrane users.

Pilot-scale ceramic ultrafiltration/nanofiltration membrane system application for caustic recovery and reuse in textile sector.

For sustainable water management, the treatment and reuse of industrial wastewater are becoming increasingly important. There have been many studies on color removal, especially from textile wastewater. However, there are deficiencies in the literature regarding highly alkaline caustic recovery and reuse in the plant. For this reason, this study examines caustic-containing textile wastewater treatment and the reuse potential of the obtained caustic chemicals with a pilot-scale ceramic membrane system. During operations, only an ultrafiltration membrane, a nanofiltration membrane, and combined ultrafiltration + nanofiltration membranes were put to use. Chemical oxygen demand, total hardness, color, total organic carbon, sodium ion concentration, and pH tests were applied to samples, and temperature and flux were recorded throughout all operations. The obtained results showed that for ultrafiltration + nanofiltration cycles, the overall average removal efficiencies were 67, 71, 42, and 92% for total organic carbon, chemical oxygen demand, total hardness, and color respectively. For only ultrafiltration cycles, the overall average removal efficiencies were 22, 36, 25, and 63% for total organic carbon, chemical oxygen demand, total hardness, and color, respectively. Sodium values in the input wastewater were around 12 mg/L on average, and nanofiltration membrane output values changed to between 7 and 11 mg/L. Based on the sodium concentration differences between inflow and outflow samples, the permeate of ceramic membrane systems has potential for reuse in facilities.

Halloysite nanotube blended nanocomposite ultrafiltration membranes for reactive dye removal.

In this paper, ultrafiltration (UF) flat sheet membranes were manufactured by introducing two diverse halloysite nanotubes (HNT) size (5 µm and 63 µm) and five different (0, 0.63, 1.88, 3.13, 6.30 wt %) ratios by wet phase inversion. Some characterization methods which are contact angle, zeta potential, viscosity, scanning electron microscopy (SEM) and Young's modulus measurements were used for ultrafiltration membranes. Synthetic dye waters which were Setazol Red and Reactive Orange were used for filtration performance tests. These dye solutions were filtered in three different pH conditions and three different temperature conditions for pH and temperature resistance to understand how flux and removal efficiency change. The best water permeability results were obtained as 190.5 LMH and 192 LMH, for halloysite nanotubes (HNT) sizes of 5 µm and 63 µm respectively. The best water and dye performance of UF membrane contains 1.88% w/w ratio of HNT, which showed increased water flux and dye flux of membranes according to different HNT concentrations including ultrafiltration membranes.