Atomic-Scale Insights into the Phase Behavior of Carbon Dioxide and Water from 313 to 573 K and 8 to 30 MPa.

We performed molecular dynamics (MD) simulations of CO2 + H2O systems by employing widely used force fields (EPM2, TraPPE, and PPL models for CO2; SPC/E and TIP4P/2005 models for H2O). The phase behavior observed in our MD simulations is consistent with the coexistence lines obtained from previous experiments and SAFT-based theoretical models for the equations of state. Our structural analysis reveals a pronounced correlation between phase transitions and the structural orderliness. Specifically, the coordination number of Ow (oxygen in H2O) around other Ow significantly correlates with phase changes. In contrast, coordination numbers pertaining to the CO2 molecules show less sensitivity to the thermodynamic state of the system. Furthermore, our data indicate that a predominant number of H2O molecules exist as monomers without forming hydrogen bonds, particularly in a CO2-rich mixture, signaling a breakdown in the hydrogen bond network's orderliness, as evidenced by a marked decrease in tetrahedrality. These insights are crucial for a deeper atomic-level understanding of phase behaviors, contributing to the well-grounded design of CO2 injection under high-pressure and high-temperature conditions, where an atomic-scale perspective of the phase behavior is still lacking.

Periodic sea-level oscillation in Tokyo Bay detected with the Tokyo-Bay seafloor hyper-kilometric submarine deep detector (TS-HKMSDD).

Meteorological-tsunami-like (or meteotsunami-like) periodic oscillation was muographically detected with the Tokyo-Bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) deployed in the underwater highway called the Trans-Tokyo Bay Expressway or Tokyo Bay Aqua-Line (TBAL). It was detected right after the arrival of the 2021 Typhoon-16 that passed through the region 400 km south of the bay. The measured oscillation period and decay time were respectively 3 h and 10 h. These measurements were found to be consistent with previous tide gauge measurements. Meteotsunamis are known to take place in bays and lakes, and the temporal and spatial characteristics of meteotsunamis are similar to seismic tsunamis. However, their generation and propagation mechanisms are not well understood. The current result indicates that a combination of muography and trans-bay or trans-lake underwater tunnels will offer an additional tool to measure meteotsunamis at locations where tide gauges are unavailable.

First results of undersea muography with the Tokyo-Bay Seafloor Hyper-Kilometric Submarine Deep Detector.

Tidal measurements are of great significance since they may provide us with essential data to apply towards protection of coastal communities and sea traffic. Currently, tide gauge stations and laser altimetry are commonly used for these measurements. On the other hand, muography sensors can be located underneath the seafloor inside an undersea tunnel where electric and telecommunication infrastructures are more readily available. In this work, the world's first under-seafloor particle detector array called the Tokyo-bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) was deployed underneath the Tokyo-Bay seafloor for conducting submarine muography. The resultant 80-day consecutive time-sequential muographic data were converted to the tidal levels based on the parameters determined from the first-day astronomical tide height (ATH) data. The standard deviation between ATH and muographic results for the rest of a 79-day measurement period was 12.85 cm. We anticipate that if the length of the TS-HKMSDD is extended from 100 m to a full-scale as large as 9.6 km to provide continuous tidal information along the tunnel, this muography application will become an established standard, demonstrating its effectiveness as practical tide monitor for this heavy traffic waterway in Tokyo and in other important sea traffic areas worldwide.

Poroelastic Modeling of a Heterogeneous Geologic Medium: A Case Study from Kanto Basin in Japan.

Vertical geological heterogeneity, such as clay content and grain size variation, may affect land subsidence caused by groundwater extraction. In order to test this hypothesis, one-dimensional pore-water mass balance and force balance equations of a water-saturated poroelastic medium were solved under different heterogeneous geological conditions. Results showed that clay content and grain size variation in sandstone could affect subsidence rates by up to an order of magnitude due to the changes in stiffness and permeability of the medium, indicating the importance of small-scale heterogeneity in subsidence simulation studies. Predicted values of subsidence were in good agreement with field measurements for two sites in the Kanto groundwater basin in Japan, showing the applicability of the model to other groundwater basins with clay-rich aquifers.

Effects of human activities and urbanization on groundwater environments: an example from the aquifer system of Tokyo and the surrounding area.

The Kanto plain that is the largest depositional plain in Japan has the largest urbanized area called Tokyo Metropolitan Area. This plain has experienced extensive groundwater withdrawals for water resources and human induced disasters such as land subsidence in the process of urbanization. Japanese national government and local governments have monitored groundwater levels and settlement of ground surface for about half a century. These data are useful not only for the prevention of these disasters but for the evaluation of the change of groundwater flow beneath the urbanized area. However, few hydrological and hydrogeological studies about the change of groundwater flow in this plain have been conducted until now except for several studies which were limited in areal extent. In this paper, changes of the distribution of hydraulic heads in the central part of this plain are discussed using the long-term groundwater level observation data to evaluate the change of groundwater flow. The temporal changes in the distribution of hydraulic heads in a major confined aquifer (the second aquifer) and the areal extent of the urbanized area for approximately 50 years can be summarized as follows. In the latter half of the 1950s, urban area was limited in the southern region of the study area and hydraulic head gradually declined from the northwest to the southeast in the study area. After the 1960s, urban area extended toward the north and groundwater in the northern part was largely abstracted until the 1980s. As a result, hydraulic heads in this area markedly declined. On the other hand, hydraulic heads in the southern part began to rise because of the restriction of groundwater withdrawals. In recent years, low hydraulic head area has been formed from the northern region to the central region. These results suggest that the groundwater flow which was affected by urbanization (groundwater withdrawals) has continued to change over several decades, even after the regulation of withdrawals, and hence, the continued monitoring of the groundwater environment is important for the sustainable use of groundwater resources.