Dynamic light scattering from lyotropic lamellar phases subjected to a flow field.

Dynamic light scattering experiments on lyotropic lamellar phases of brine and surfactant subjected to a flow field have been realized. The obtained results reveal that the relaxation times measured depend strongly on the velocity of the flow. This dependence is indicative of an increase of the effective elasticity modulus K and a decrease of the effective compressibility modulus (-)B of the lamellar phase with the flow velocity. This leads to the conclusion that the shear can induce a suppression of the undulation fluctuations of the bilayers of the lamellar phase. Our results show also that the rigidity of the membranes decreases as the salt concentration of the sample increases.

Shear-induced first-order sponge-to-lamellar transition in a lyotropic surfactant system.

We report a shear-induced sponge (L3) to lamellar (L(alpha)) transition in a surfactant system. Under a constant shear rate, after a delay time t(n) we observe random nucleation and subsequent growth of the L(alpha) phase, demonstrating that the shear-induced transition is first order. A simple argument for the energy of a two-dimensional nucleus accounts for the observed delay and its shear-rate dependence.

Observations of the collapse of dilute lyotropic lamellar phases under shear flow

Experimental evidence of the collapse of dilute lamellar phases due to shear flow is presented. Two systems are used: one composed of brine and an ionic surfactant, and another composed of water, a nonionic surfactant, and cosurfactant. We observe this transition for a range of lamellar spacings and brine salinity. The results are in reasonable agreement with recent theory in which the suppression of fluctuations by shear plays an important role.

Coupling between flow and structure for a lamellar surfactant phase

The flow-structure relation of lamellar phases is studied using rheometry and cross-polarized microscopy under flow. The equilibrium phases show different defects. Low salinities lead to very viscous, "onion" phases, whereas at high salinity, a low viscosity plane lamellar phase is found. Under shear, the latter shows a sudden transition to a viscoelastic gel, with a texture and viscosity very similar to that of the onions. Gelation occurs after a certain delay time, increasing rapidly with salinity, by the nucleation of onions. This allows one to relate the delay time to the defect energy.