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1.
Appl Radiat Isot ; 210: 111343, 2024 Aug.
Article in English | MEDLINE | ID: mdl-38739998

ABSTRACT

This paper aimed to conduct a systematic review of 26 published articles from 13 different regions in the Republic of Yemen related to the study of natural radioactivity (NORM) and enhanced artificial radioactivity (TENORM). The study relied on the analysis of various sample types, including air, groundwater, surface water, hot spring water, soil, sand, rocks, building materials, and oil field samples. It also analyzed the study areas, the types of detectors employed, and the study's timeframe. The analytical results raised significant concerns regarding the high levels of radioactivity observed in many of the studied regions. Moreover, some regions indicated the absence of any prior radiological study, despite apparent effects on the population and the environment, which suggest the presence of potential radionuclide concentration. Based on this study, it is strongly recommended that researchers conduct further radiological studies in regions previously studied over extended periods and in areas where no prior radiological studies have been conducted to assess potential radionuclide concentration.

2.
Sci Rep ; 12(1): 10647, 2022 06 23.
Article in English | MEDLINE | ID: mdl-35739169

ABSTRACT

MgO-Bi2-xCrxO3 nanocomposites for x = 0 and 0.07 were fabricated using the solvent-deficient route. X-ray diffraction method, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA) and UV-Vis spectroscopy were employed to study the properties. The samples were also evaluated for the antibacterial activity. The x = 0 sample showed a dominant monoclinic crystalline structure of [Formula: see text] phase. No peaks attributed to MgO were observed. Cr-doped [Formula: see text] in which Bi was substituted showed that [Formula: see text] phase was also present in the [Formula: see text] composite. The Scherrer formula was employed to determine the crystallite size of the samples. The Cr-doped sample showed a decrease in the crystallite size. The microstructures of the non-doped MgO-Bi2O3 and MgO-Bi1.93Cr0.07O3 composites consisted of micrometer sized grains and were uniformly distributed. Direct transition energy gap, [Formula: see text] decreased from 3.14 to 2.77 eV with Cr-doping as determined from UV-Vis spectroscopy. The Cr-doped [Formula: see text] nanocomposites exhibited two energy gaps at 2.36 and 2.76 eV. The antibacterial activity was determined against gram-negative bacteria (Salmonella typhimurium and Pseudomonas aeruginosa) and gram-positive bacteria (Staphylococcus aureus) by disc diffusion method. Cr-doping led to a decrease in inhibitory activity of MgO-Bi2-xCrxO3 nanocomposite against the various types of bacteria.


Subject(s)
Magnesium Oxide , Nanocomposites , Anti-Bacterial Agents/chemistry , Anti-Bacterial Agents/pharmacology , Magnesium Oxide/pharmacology , Nanocomposites/chemistry , Solvents , Staphylococcus aureus
3.
Dalton Trans ; 46(10): 3393-3399, 2017 Mar 07.
Article in English | MEDLINE | ID: mdl-28239712

ABSTRACT

In the present study, beta-cobalt hydroxide (ß-Co(OH)2) electrodes of various nanostructures and surface areas, viz. nano-rhombuses (NRs), nano-plates (NPs), and nano-grass (NGs), have been synthesized directly onto a stainless-steel (SS) substrate using a simple, economical and binder-free chemical solution-process, utilizing three cobalt precursor salts, i.e. cobalt acetate, cobalt chloride, and cobalt nitrate, respectively. Structural elucidation proves the crystallite size, type and phase-purity of ß-Co(OH)2, whereas the surface morphology analysis supports the evolution of the above mentioned nanostructures of various surface areas. The electrochemical pseudocapacitor performance investigation demonstrates a specific capacitance (Sc) of 367 F g-1 at 1 mA cm-2 for the NP-type morphology, which is higher than that that displayed by the other morphologies. This change in Sc value is attributed to different charge transfer resistance values, which have been obtained from electrochemical impedance spectroscopy spectra. Finally, we attempt to correlate the relationship between the surface morphology, i.e. surface area, and the charge transfer resistance with the obtained specific capacitance value of the respective electrode.

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