ABSTRACT
Radiostrontium (r-Sr: 90Sr) is one of the primary fission products in nuclear power plants and generates liquid radioactive waste when intermixed to the aqueous matrix. Therefore, separation or preconcentration of r-Sr from the aqueous matrices is necessary for environmental monitoring or nuclear forensics. The solid-phase extraction (SPE) approach is prevalently used for r-Sr isolation and to design matrix-specific methods, while generalized SPE-assisted operating protocols are not proposed by far. In the current work, four different SPEs, namely AnaLig Sr-01, Eichrom Sr, Triskem TK100, and Eichrom DGA, were evaluated for selective separation of Sr from aqueous matrices. Operating variables, e.g., solution acidity, washing solvent, eluent-type or volume, loading or elution flow-rate, were varied to optimize the SPEs performance. The objective was to ascertain the operating variables for maximum Sr-separation yield from aqueous environmental samples with the SPEs mentioned above. In addition, the Sr-separation efficiency of SPEs was evaluated by calculating the separation factor (SFSr/M) between Sr and interfering elements to r-Sr (M = Ca, Mg, Ba, or Y), and the Sr-retention capacity of the SPEs was determined. Finally, the optimized operating variables for the evaluated SPEs were used to construct protocols for r-Sr separation from aqueous matrices. Real 90Sr contaminated aqueous samples from the Chernobyl nuclear power plant cooling pond were treated by those protocols, and the results are validated comparing with the IAEA-recommended classical protocol. All the SPEs were able to isolate Sr at varying extents from matrices at the optimum conditions, even at much higher contents of interfering elements. Eichrom Sr or AnaLig Sr-01 showed better Sr-retention capability among the SPEs, while Triskem TK100 showed superiority over other SPEs regarding Sr-selectivity.
Subject(s)
Radioactive Waste , Solid Phase Extraction , Environmental Monitoring , Solvents , WaterABSTRACT
The release of radiocesium (r-Cs) into natural aqueous systems is of concern because of its extended solubility as an alkaline metal ion and its facile incorporation into living beings. A technique for the selective separation of Cs from an aqueous matrix using dual solid-phase extraction (SPE) systems in a series is proposed in this paper. The SPEs equipped with chelates (Nobias Chelate-PA1 and Nobias Chelate-PB1), an ion-exchange resin (Nobias Ion SC-1), or macrocycles (MetaSEP AnaLig Cs-01 and MetaSEP AnaLig Cs-02) were evaluated in terms of selectivity and retention/recovery behavior toward Cs and other potentially competing ions (Li, Na, K, Rb, Ba, Ca, Mg, and Sr). The simulated solution of 133Cs, a chemical analog of r-Cs, was used to optimize the separation process. Operating parameters such as pH (3-13), flow rate (0.2-5.0 mL min-1), and elution behavior (HCl, 0.1-5.0 mol L-1) were optimized to ensure maximum removal of Cs from the aqueous matrices. The dual SPE system comprised Nobias Chelate-PB1 that minimized the competing impact of ions, while selective Cs retention was attained with MetaSEP AnaLig Cs-02. The proposed process was verified using real r-Cs-contaminated water from Fukushima, Japan, to observe the quantitative separation and preconcentration of r-Cs from the complex matrices.
