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1.
PLoS One ; 17(11): e0275467, 2022.
Article in English | MEDLINE | ID: mdl-36322576

ABSTRACT

This paper aimed to investigate the temperature effect on photovoltaic (PV) cell parameters. The PV cell parameters such as series and parallel resistances, diode ideality factor, and diode saturation current, are not considered in the reported stepwise modeling. The present work aims to improve available models used in the modeling and simulation of PV modules to support the researcher and power project developer. All the required temperature-dependent parameters are determined to model the simulated PV module with high accuracy using Simulink/MATLAB software. To validate the method, a 36-cell-50W solar panel with different radii of curvature is set up to assess solar power outputs under varying irradiance and temperature conditions. For the present application, the Tabuk region (Saudi Arabia) is chosen based on its location and climatic conditions. The method provided conformity to the measured power outputs for varying Global Horizontal Irradiance (GHI) and temperature conditions. The maximum power output of the PV module increases from 14.4 W to 25.8 W when the received solar power density varies from 307 W/m2 to 526 W/m2 depending on the level of curvature starting from a semi-cylindrical shape to a vaulted shape to a flat shape. The curved PV module shows slightly higher power variation with temperature as compared to the flat one. Above 25°C, the power output is about 20% less at a maximum temperature of 65°C. When the temperature drops below 25°C, the power outputs increase about 6% and 11.5% for corresponding temperatures of 15°C and 5°C, respectively.


Subject(s)
Electric Power Supplies , Solar Energy , Computer Simulation , Temperature , Sunlight
2.
Polymers (Basel) ; 14(18)2022 Sep 14.
Article in English | MEDLINE | ID: mdl-36145980

ABSTRACT

In this work, solid flexible polymer blend electrolytes (PBE) composed of polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) with different amounts of sodium thiocyanate (NaSCN) salt mixed in double-distilled water (solvent) are prepared via solution casting method. The obtained films are characterized using several techniques. The study of the surface morphology of the polymer blend salt complex films via the POM technique reveals the presence of amorphous regions due to the NaSCN effect. FTIR spectra studies confirm the complex formation between PVA, PVP, and NaSCN. The addition of 20 wt% NaSCN salt in the composition PVA: PVP (50:50 wt%) polymer blend matrix leads to an increase in the number of charge carriers and thus improves the ionic conductivity. The ionic conductivity of each polymer blend electrolyte was studied using the electrochemical impedance spectroscopy (EIS) method. The highest room temperature ionic conductivity of 8.1 × 10-5 S/cm S cm-1 is obtained for the composition of PVA: PVP (50:50 wt%) with 20 wt% NaSCN. LSV test shows the optimized ion-conducting polymer blend electrolyte is electrochemically stable up to 1.5 V. TNM analysis reveals that 99% of ions contribute for the conductivity against 1% of electrons only in the highly conductive polymer electrolyte PVA: PVP (50:50 wt%) + 20 wt% NaSCN. A supercapacitor device was fabricated using the optimized ion-conducting polymer blend film and graphene oxide (GO) coated electrodes. The GCD curve clearly reveals the behavior of an ideal capacitor with less Faradic process and low ESR value. The columbic efficiency of the GO-based system is found to be 100%, the GO-based electrode exhibits a specific capacitance of 12.15 F/g and the system delivers the charge for a long duration. The specific capacitance of the solid-state supercapacitor cell was found to be 13.28 F/g via the CV approach close to 14.25 F/g obtained with EIS data at low frequency.

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