Do bromine and surface-active substances influence the coastal atmospheric particle growth?

New particle formation (NPF) is considered a major source of aerosol particles and cloud condensation nuclei (CCN); however, our understanding of NPF and the subsequent particle growth mechanisms in coastal areas remains limited. This study provides evidence of frequent NPF events followed by particle growth in the middle Adriatic Sea during the summer months at the coastal station of Rogoznica in Croatia. To our knowledge, this is the first study to report such events in this region. Our research aims to improve the understanding of NPF by investigating particle growth through detailed physicochemical characterization and event classification. We used a combination of online measurements and offline particle collection, followed by a thorough chemical analysis. Our results suggest the role of bromine in the particle growth process and provide evidence for its involvement in combination with organic compounds. In addition, we demonstrated the significant influence of surface-active substances (SAS) on particle growth. NPF and particle growth events have been observed in air masses originating from the Adriatic Sea, which can serve as an important source of volatile organic compounds (VOC). Our study shows an intricate interplay between bromine, organic carbon (OC), and SAS in atmospheric particle growth, contributing to a better understanding of coastal NPF processes. In this context, we also introduced a new approach using the semi-empirical 1st derivative method to determine the growth rate for each time point that is not sensitive to the nonlinear behavior of the particle growth over time. We observed that during NPF and particle growth event days, the OC concentration measured in the ultrafine mode particle fraction was higher compared to non-event days. Moreover, in contrast to non-event days, bromine compounds were detected in the ultrafine mode atmospheric particle fraction on nearly all NPF and particle growth event days. Regarding sulfuric acid, the measured sulfate concentration in the ultrafine mode atmospheric particle fraction on both NPF event and non-event days showed no significant differences. This suggests that sulfuric acid may not be the primary factor influencing the appearance of NPF and the particle growth process in the coastal region of Rogoznica.

Highly Time-Resolved Apportionment of Carbonaceous Aerosols from Wildfire Using the TC-BC Method: Camp Fire 2018 Case Study.

The Camp Fire was one of California's deadliest and most destructive wildfires, and its widespread smoke threatened human health over a large area in Northern California in November 2018. To analyze the Camp Fire influence on air quality on a 200 km distant site in Berkeley, highly time-resolved total carbon (TC), black carbon (BC), and organic carbon (OC) were measured using the Carbonaceous Aerosol Speciation System (CASS, Aerosol Magee Scientific), comprising two instruments, a Total Carbon Analyzer TCA08 in tandem with an Aethalometer AE33. During the period when the air quality was affected by wildfire smoke, the BC concentrations increased four times above the typical air pollution level presented in Berkeley before and after the event, and the OC increased approximately ten times. High-time-resolution measurements allow us to study the aging of OC and investigate how the characteristics of carbonaceous aerosols evolve over the course of the fire event. A higher fraction of secondary carbonaceous aerosols was observed in the later phase of the fire. At the same time, the amount of light-absorbing organic aerosol (brown carbon) declined with time.

Two-year-long high-time-resolution apportionment of primary and secondary carbonaceous aerosols in the Los Angeles Basin using an advanced total carbon-black carbon (TC-BC(λ)) method.

In recent years, carbonaceous aerosols (CA) have been recognized as a significant contributor to the concentration of particles smaller than 2.5 µm (i.e., PM2.5), with a negative impact on public health and Earth's radiative balance. In this study, we present a method for CA apportionment based on high-time-resolution measurements of total carbon (TC), black carbon (BC), and spectral dependence of absorption coefficient using a recently developed Carbonaceous Aerosol Speciation System (CASS). Two-year-long CA measurements at two different locations within California's Los Angeles Basin are presented. CA was apportioned based on its optical absorption properties, organic or elemental carbon composition, and primary or secondary origin. We found that the secondary organic aerosols (SOA), on average, represent >50 % of CA in the study area, presumably resulting from the oxidation of anthropogenic and biogenic volatile organic components. Remarkable peaks of SOA in summer afternoons were observed, with a fractional contribution of up to 90 %. On the other hand, the peak of primary emitted CA, consisting of BC and primary organic aerosol (POA), contributed >80 % to the CA during morning rush hours on winter working days. The light absorption of BC dominated over the brown carbon (BrC), which contributed to 20 % and 10 % of optical absorption at the lower wavelength of 370 nm during winter nights and summer afternoons, respectively. The highest contribution of BrC, up to 50 %, was observed during the wildfire periods. Although the uncertainty levels can be high for some CA components (such as split between primary emitted and secondary formed BrC during winter nights), further research focused on the optical properties of CA at different locations may help to better constrain the parameters used in CA apportionment studies. We believe that the CASS system combined with the apportionment method presented in this study can offer simplified and cost-effective insights into the composition of carbonaceous aerosols.

Elemental compositions of particulate matter retained on air condition unit's filters at Greater Doha, Qatar.

Elemental composition of airborne dust samples retained by internal filters of air condition units (ACUs) was determined at 12 locations of Doha city, state of Qatar. Twenty-four elements: Al, Ca, Mg, Fe, Na, K, Ti, Zn, P, Sr, Mn, Ba, Cu, Cr, Ni, Pb, V, Mo, Li, Co, Sb, As, Cd, Be, were analysed by ICP-OES technique after acid digestion of the samples. The analysed components reflect 20.6% of the total sample mass. Similar or lower concentration values have been found for As, Cd, Cr, Cu, Mn, Ni, Pb, V, Zn, Al, and Fe compared to the international context of upper crust concentrations, NIST SRM (urban dust), published local dust information of outdoor, and surface terrestrial deposit (STD) counted for 7.2, 0.7, 91.8, 192.8, 369.7, 68.6, 65.3, 52.1, 824.3, 19,791, 20,508 mg/kg, respectively. The coefficient of correlation (p ≤ 0.05) showed significant association of ACUs dust elemental compositions with the main components of the local earth crust and surface deposits, ranging from the lowest 0.77 (Mg-Fe) to the highest 0.98 (Al-Fe), while Ni and V, typical anthropogenic pollutants, are also strongly correlated (0.86). These strong correlation relationships can be interpreted as the contribution of outdoor particulate to the indoor dust. Dendrogram of metal/Al ratios, based on Euclidean distance calculation and average linkage clustering method, distinguished three typical groups. Studying the enrichment factors of the three groups indicated elevated levels of Zn (131), Pb (49), Cu (32), Cd (8) and Ni (5) found indoors compared to the background composition of STD especially at locations in the industrial zone. The major elemental composition of the samples reflects the typical mineral composition of the local dust, while the trace composition demonstrates the influence of indoor sources. The collected ACU filter dust samples show significant contribution of outdoor mineral particles, non-exhaust traffic emission, industrial sources, as well as the influence of indoor activity such as smoking.

PAH concentrations and exposure assessment from house dust retained in air-conditioning filters collected from Greater Doha, Qatar.

Polycyclic aromatic hydrocarbons (PAHs) bound in dust retained in air-conditioning unit filters from 13 households in Greater Doha, Qatar, were quantified using GC-MS spectrometry. The median concentrations of ∑16PAH and ∑7PAH were 218.0 ng g-1 (± 125.3) and 112.1 ng g-1 (± 60.2) dry weight, respectively. Results show that except one sample, three- and four-benzene-ring PAHs were dominant in all dust samples. Phenanthrene, anthracene, pyrene, benzene(a)anthracene, and chrysene were dominant in 12 samples with maximum concentrations of 69.7 ng g-1 (± 24.0), 92.9 ng g-1 (± 28.1), 60.4 ng g-1 (± 14.7), 38.6 ng g-1 (± 7.3), and 14.7 ng g-1 (± 3.5), respectively. Benzo(k)fluoranthene has the most abundance of the quantified PAHs in the dust samples accounting for 19% of the total PAHs. Although Kriging interpolation shows a spatial variation of PAHs from north to south of Greater Doha, the mean concentrations in both directions were statically insignificant. Five samples displayed levels of benzo(a)pyrene (BaP) with maximum and median concentrations at 110.8 ng g-1 and 49.9 (± 28.4) dry weight, respectively. Benzo(a)pyrene equivalent approach [Formula: see text] was applied to assess carcinogenic exposure, and the resulting values (1.3-116.4 ng g-1) indicate that the levels observed were below the values reported for other countries within the region. Estimated daily ingestion (EDI) rates of PAHs retained in ACU filters were assessed for five age-groups < 1, 1-2, 3-6, 11-16, and > 19 years and were 0.39 (± 0.1), 0.33 (± 0.1), 0.20 (± 0.02), 0.07 (± 0.02), and 0.05 (± 0.01) ng kg-1/day, respectively. Source apportionment estimate indicates PAHs bound in dust retained in ACU filters are originated from pyrogenic sources.

Health implications of atmospheric aerosols from asbestos-bearing road pavements traditionally used in Southern Brazil.

Serpentine and amphibole asbestos occur naturally in certain geologic settings worldwide, most commonly in association with ultramafic rocks, along associated faults. Ultramafic rocks have been used in Piên County, Southern Brazil for decades for the purpose of road paving in rural and urban areas, but without the awareness of their adverse environmental and health impact. The aim of this study was the chemical characterization of aerosols re-suspended in two rural roads of Piên, paved with ultramafic rocks and to estimate the pulmonary deposition of asbestos aerosols. Bulk aerosol samples were analyzed by means of X-ray fluorescence spectrometry and X-ray diffraction analysis, in order to characterize elemental composition and crystallinity. Single-particle compositions of aerosols were analyzed by computer-controlled electron-probe microanalysis, indicating the presence of a few percentages of serpentine and amphibole. Given the chemical composition and size distribution of aerosol particles, the deposition efficiency of chrysotile, a sub-group of serpentine, in two principal segments of the human respiratory system was estimated using a lung deposition model. As an important finding, almost half of the inhaled particles were calculated to be deposited in the respiratory system. Asbestos depositions were significant (∼25 %) in the lower airways, even though the selected breathing conditions (rest situation, nose breathing) implied the lowest rate of respiratory deposition. Considering the fraction of inhalable suspended chrysotile near local roads, and the long-term exposure of humans to these aerosols, chrysotile may represent a hazard, regarding more frequent development of lung cancer in the population of the exposed region.

Determination of trace elements in lithium niobate crystals by solid sampling and solution-based spectrometry methods.

Solid sampling (SS) graphite furnace atomic absorption spectrometry (GFAAS) and solution-based (SB) methods of GFAAS, flame atomic absorption spectrometry (FAAS), inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS) were elaborated and/or optimized for the determination of Cr, Fe and Mn trace elements used as dopants in lithium niobate optical crystals. The calibration of the SS-GFAAS analysis was possible with the application of the three-point-estimation standard addition method, while the SB methods were mostly calibrated against matrix-matched and/or acidic standards. Spectral and non-spectral interferences were studied in SB-GFAAS after digestion of the samples. The SS-GFAAS method required the use of less sensitive spectral lines of the analytes and a higher internal furnace gas (Ar) flow rate to decrease the sensitivity for crystal samples of higher (doped) analyte content. The chemical forms of the matrix produced at various stages of the graphite furnace heating cycle, dispensed either as a solid sample or a solution (after digestion), were studied by means of the X-ray near-edge absorption structure (XANES). These results revealed that the solid matrix vaporized/deposited in the graphite furnace is mostly present in the metallic form, while the dry residue from the solution form mostly vaporized/deposited as the oxide of niobium.

Particulate matter analysis at elementary schools in Curitiba, Brazil.

The particulate matter indoors and outdoors of the classrooms at two schools in Curitiba, Brazil, was characterised in order to assess the indoor air quality. Information concerning the bulk composition was provided by energy-dispersive x-ray fluorescence (EDXRF). From the calculated indoor/outdoor ratios and the enrichment factors it was observed that S-, Cl- and Zn-rich particles are of concern in the indoor environment. In the present research, the chemical compositions of individual particles were quantitatively elucidated, including low-Z components like C, N and O, as well as higher-Z elements, using automated electron probe microanalysis low Z EPMA. Samples were further analysed for chemical and morphological aspects, determining the particle size distribution and classifying them according to elemental composition associations. Five classes were identified based on major elemental concentrations: aluminosilicate, soot, organic, calcium carbonate and iron-rich particles. The majority of the respirable particulate matter found inside of the classroom was composed of soot, biogenic and aluminosilicate particles. In view of the chemical composition and size distribution of the aerosol particles, local deposition efficiencies in the human respiratory system were calculated revealing the deposition of soot at alveolar level. The results showed that on average 42% of coarse particles are deposited at the extrathoracic level, whereas 24% are deposited at the pulmonary region. The fine fraction showed a deposition rate of approximately 18% for both deposition levels.

Size distribution, pulmonary deposition and chemical composition of Hungarian biosoluble glass fibers.

Compared to spherical particles, inhaled fibers may cause enhanced adverse health effects because of their specific shape, thus acting as so-called physical carcinogens. The chemical composition of fibers plays a determining role on the durability and hence may play a potential role in related health effects due to their toxic components. The physical properties, that is, length, diameter, and size distribution, and the chemical composition of fiberglass materials sampled at a Hungarian glass wool factory were investigated. The morphology of the particles was studied by optical microscopy and scanning electron microscopy (SEM), while for the chemical analysis instrumental neutron activation analysis (INAA) and SEM combined with energy-dispersive x-ray analysis (EDX) were used. Deposition fractions of the fibers in different regions of the lung and in the whole human respiratory system were computed by a stochastic lung deposition model for different flow rates and equivalent diameters, using experimentally determined size distributions.

Characterization of atmospheric particles by electron probe X-ray microanalysis.

Microchemical glass standards were used to validate a quantitation method based on peak-to-background (P/B) ratios from electron probe x-ray microanalysis spectra. This standardless method was applied to the determination of concentrations of individual particles from Malpha or Lalpha lines, as well as from Kalpha lines. The algorithm was tested on particulate glass samples for diameters ranging from 1 to 20 microm. The determined concentrations did not depend on particle size. The certified values for elements were well matched, except for Na, which may migrate under electron bombardment. Finally, classification of qualitative results obtained for aerosol particles was completed by the P/B quantitative method.