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Langmuir ; 29(10): 3320-7, 2013 Mar 12.
Article in English | MEDLINE | ID: mdl-23421732

ABSTRACT

This work describes a simple, versatile, and inexpensive procedure to prepare optically transparent carbon electrodes, using proteins as precursors. Upon adsorption, the protein-coated substrates were pyrolyzed under reductive conditions (5% H2) to form ultrathin, conductive electrodes. Because proteins spontaneously adsorb to interfaces forming uniform layers, the proposed method does not require a precise control of the preparation conditions, specialized instrumentation, or expensive precursors. The resulting electrodes were characterized by a combination of electrochemical, optical, and spectroscopic means. As a proof-of-concept, the optically transparent electrodes were also used as substrate for the development of an electrochemical glucose biosensor. The proposed films represent a convenient alternative to more sophisticated, and less available, carbon-based nanomaterials. Furthermore, these films could be formed on a variety of substrates, without classical limitations of size or shape.


Subject(s)
Carbon/chemistry , Electrodes , Nanostructures/chemistry , Proteins/chemistry , Adsorption , Biosensing Techniques/methods , Glucose/analysis , Glucose/chemistry
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