Removal of pharmaceuticals from nitrified urine.

In this study, granular activated carbon (GAC) was examined for the removal of five of the most commonly detected pharmaceuticals (naproxen, carbamazepine, acetaminophen, ibuprofen and metronidazole) from a nitrified urine to make the urine-derived fertiliser nutrient safe for food crops. Batch experiments were conducted to investigate the adsorption kinetics that described the removal of micropollutants (equal concentrations of 0.2 mM) from the synthetic nitrified urine at different GAC dosages (10-3000 mg/L). Artificial neural network modelling was also used to predict and simulate the removal of pharmaceuticals from nitrified urine. Langmuir and Freundlich isotherm models described the equilibrium data, with the Langmuir model providing slightly higher correlations. At the highest dose of 3000 mg/L GAC, all the pharmaceuticals showed a removal rates of over 90% after 1 h of adsorption time and 99% removal rates after 6 h of adsorption time. This study concludes that GAC is able to remove the targeted xenobiotics without affecting the concentration of N and P in the urine, suggesting that nitrified urine could be safely used as a nutrient product in future.

Novel hole-pillar spacer design for improved hydrodynamics and biofouling mitigation in membrane filtration.

Feed spacers are the critical components of any spiral-wound filtration module, dictating the filtration performance. Three spacer designs, namely a non-woven commercial spacer (varying filament cross-section), a symmetric pillar spacer, and a novel hole-pillar spacer (constant filament diameter) were studied using Direct Numerical Simulations (DNS), 3-D printed and subsequently experimentally tested in a lab-scale ultrafiltration set-up with high biofouling potential feed water at various feed pressures. Independent of the applied pressure, the novel hole-pillar spacer showed initially the lowest feed channel pressure drop, the lowest shear stress, and the highest permeate flux compared to the commercial and pillar spacers. Furthermore, less biofilm thickness development on membrane surface was visualized by Optical Coherent Tomography (OCT) imaging for the proposed hole-pillar spacer. At higher feed pressure, a thicker biofilm developed on membrane surface for all spacer designs explaining the stronger decrease in permeate flux at high pressure. The findings systematically demonstrated the role of various spacer designs and applied pressure on the performance of pre-treatment process, while identifying specific shear stress distribution guidelines for engineering a new spacer design in different filtration techniques.

Energy efficient 3D printed column type feed spacer for membrane filtration.

Modification of the feed spacer design significantly influences the energy consumption of membrane filtration processes. This study developed a novel column type feed spacer with the aim to reduce the specific energy consumption (SEC) of the membrane based water filtration system. The proposed spacer increases the clearance between the filament and the membrane (reducing the spacer filament diameter) while keeping the same flow channel thickness as compared to a standard non-woven symmetric spacer. Since the higher clearance reduces the flow unsteadiness, column type nodes were added in the spacer structure as additional vortex shading bodies. Fluid flow behaviour in the channel for this spacer was numerically simulated by 3D CFD studies and then compared with the standard spacer. The numerical results showed that the proposed spacer substantially reduced the pressure drop, shear stress at the constriction region and shortened the dead zone. Finally, these findings were confirmed experimentally by investigating the filtration performances using the 3D printed prototypes of these spacers in a lab-scale filtration module. It is observed that the column spacer reduced the pressure drop by three times and doubled the specific water flux. 2D OCT (Optical Coherence Tomography) scans of the membrane surface acquired after the filtration revealed much lower biomass accumulation using the proposed spacer. Consequently, the SEC for the column spacer was found about two folds lower than the standard spacer.

Forward osmosis system analysis for optimum design and operating conditions.

Low energy consumption and less fouling propensity of forward osmosis (FO) processes have been attractive as a promising water filtration technology. The performance of this process is however significantly influenced by its operating conditions. Moreover, these operating parameters have both favourable and adverse effects on its performance. Therefore, it is very important to optimize its performance for efficient and economic operation. This study aims to develop a software to analyze a full-scale FO system for optimum performance. A comprehensive theoretical framework was developed to estimate the performance of FO system. Analysis results were compared with the experimental results to validate the models. About 5% deviation of simulation results and the experimental findings shows a very good agreement between them. A novel optimization algorithm was then developed to estimate the minimum required draw solution (DS) inlet flowrate and the number of elements in a pressure vessel to attain the design objectives (i.e. desired final DS concentration and recovery rate at a specific feed solution (FS) flowrate). A detailed parametric study was also conducted to determine the optimum operating conditions for different objectives. It showed that for a specific design objective, higher recovery rate can be achieved by increasing the DS flowrate and number of elements in a pressure vessel. In contrast, lower final concentration can be obtained by lowering the DS flowrate and increasing the number of elements. Finally, a MATLAB based software with graphical user interface was developed to make the analysis process easier and efficient.

Forward osmosis membrane modular configurations for osmotic dilution of seawater by forward osmosis and reverse osmosis hybrid system.

This study evaluates various options for full-scale modular configuration of forward osmosis (FO) process for osmotic dilution of seawater using wastewater for simultaneous desalination and water reuse through FO-reverse osmosis (RO) hybrid system. Empirical relationship obtained from one FO membrane element operation was used to simulate the operational performances of different FO module configurations. The main limiting criteria for module operation is to always maintain the feed pressure higher than the draw pressure throughout the housing module for safe operation without affecting membrane integrity. Experimental studies under the conditions tested in this study show that a single membrane housing cannot accommodate more than four elements as the draw pressure exceeds the feed pressure. This then indicates that a single stage housing with eight elements is not likely to be practical for safe FO operation. Hence, six different FO modular configurations were proposed and simulated. A two-stage FO configuration with multiple housings (in parallel) in the second stage using same or larger spacer thickness reduces draw pressure build-up as the draw flow rates are reduced to half in the second stage thereby allowing more than four elements in the second stage housing. The loss of feed pressure (pressure drop) and osmotic driving force in the second stage are compensated by operating under the pressure assisted osmosis (PAO) mode, which helps enhance permeate flux and maintains positive pressure differences between the feed and draw chamber. The PAO energy penalty is compensated by enhanced permeate throughput, reduced membrane area, and plant footprint. The contribution of FO/PAO to total energy consumption was not significant compared to post RO desalination (90%) indicating that the proposed two-stage FO modular configuration is one way of making the FO full-scale operation practical for FO-RO hybrid system.