The fate of leaked heavy metals in the urban environment under different persistence and precipitation scenarios.

The use of tobacco will lead to the littering of a large number of filters, and the leakage of pollutants from them into the urban environment is a serious concern. The aim of this study was to analyze the leakage of heavy metals from filter and estimate the annual concentration of pollution leakage in different waste routes and different climatic conditions. The results showed that the highest and lowest density of filter in the studied urban environment were 0.51 and 0.01 number/m2, respectively. According to the estimated annual production of 306 million cigarette butts in the studied area, the leakage of the studied metals was estimated to be 401 g. The share of copper, chromium, and cadmium from the total leakage was 67%, 8.3%, and 1.88%, respectively. The leakage of studied metals in rainy conditions was 2.86 times more than sunny conditions. In different scenarios, the minimum and maximum annual leakage of metals were estimated 23,043 and 350,419 mg/year, respectively. Filters are a little but important source of heavy metal emission into the urban environment, the amount of pollution from which is affected by the consumers' behavior and the efficiency of the urban cleaning system. Education on the correct disposal of filters and increasing the efficiency of the urban cleaning system will lead to a reduction in pollution caused by tobacco consumption.

Quality variations of leachate resulting from cigarette filter recycling as a challenge for its management.

Recycling is known as a solution for cigarette filter management, but this may cause the release of trapped pollutants in it. Cigarette smoke toxins and chemicals that trapped in the cigarette filter can accumulate in the recycling leachate. In this study, littered cigarette filters and freshly smoked cigarette filters were recycled and the resulting leachate was analyzed. The results showed that the minimum and maximum Chemical Oxygen Demand (COD) of the studied leachates were 2100 mg/L and 11,300 mg/L, respectively. The maximum temporal variation in the studied leachate quality was 74.28%, but the maximum spatial variation was 314.2%. COD in the freshly smoked sample was 2600-9200 mg/L more than the littered samples. The average concentration of chromium, lead, nickel, and cadmium in littered samples was 0.023, 0.024, 0.045, and 0.019 mg/L, respectively. Environmental conditions such as humidity, the efficiency of the urban cleaning system in reducing the resistance of littered filters, the difference in the quality of the filter and tobacco, and the difference in smoking behaviors were effective in this variation. Reducing the toxicity of cigarette smoke and improving the efficiency of the urban cleaning system can lead to the same quality, but leachate treatment is necessary to reduce the environmental risk.

Impact of Covid-19 pandemic lockdown on the urban litter and clean environment index.

Changing the level of pollution in the urban environment is one of the consequences of Covid-19. Litter are one of the most important urban pollutants affected by the Covid-19 pandemic. In this research, the pollution level of urban areas during the Covid-19 pandemic was investigated by studying the urban environment. To this end, the protocol of observation and counting was used and litter were studied in two groups including common litter and Covid-19 related litter in Yasuj, Iran. The results were interpreted based on the clean environment index (CEI). The time of observation was selected based on the peak of the disease and the decline in the incidence rate. The results showed that on average, at the peak of the disease, the density of the litter was reduced by 19% compared to the low lockdown related to Covid-19. The CEI on average was 4.76 at the peak of the disease that was interpreted in the clean status, while the CEI on average was 5.94 at the low lockdown related to Covid-19 so interpreted in the moderate status. Among urban land uses, recreational areas with a difference of more than 60% showed the greatest impact caused by Covid-19, while in commercial areas this difference was less than 3%. The effect of Covid-19 related litter on the calculated index was 73% in the worst case and 0.8% in the lowest case. Although Covid-19 decreased the number of litter in urban areas, the emergence of Covid-19 lockdown related litter was a cause for concern and led to increasing the CEI.

Effect of educational intervention based on health belief model on nurses' compliance with standard precautions in preventing needle stick injuries.

BACKGROUND: The increasing prevalence of needle stick injuries among nurses and the arising risks double the need to pay attention to improve their knowledge and change their behavior using effective educational models. The present study aimed to investigate the effect of educational intervention based on the health belief model on nurses' compliance with standard precautions in preventing needle stick injuries. METHODS: This quasi-experimental study was conducted on 110 nurses working in medical training centers in Shiraz and Fasa in 2019. Subjects were selected using a simple sampling method and were randomly divided into two interventions (n = 55) and control (n = 55). The intervention included 7 sessions of 50-55 min. Before and 3 months after the intervention, the health belief model questionnaire was completed by both groups. The data were analyzed using SPSS software version 22 through chi-square, independent, and paired t-tests (P < 0.05). RESULTS: Based on independent and paired t-tests, there was no significant difference between the control and intervention groups regarding the mean score of health belief model constructs before the intervention. However, there was a significant difference regarding the mentioned scores 3 months after the educational intervention. Based on the paired t-test, the mean score of awareness, perceived sensitivity, perceived severity, perceived benefits, self-efficacy, cues to action, and behavioral performance in the intervention group significantly increased after the educational intervention (P < 0.05). Also, there was a significant decrease in perceived barriers (P < 0.05). CONCLUSION: It is recommended to apply the proposed model as an effective and cost-effective method along with other methods in training programs for nurses and other health workers exposed to invasive procedures, contaminated blood, and secretions.

Spatial and temporal variation of CBPI and leakage of heavy metals from cigarette butts into the urban environment.

More than 5 trillion cigarettes are produced in the world every year. This hazardous waste is one of the most important litter in the environment. The purpose of this study was to investigate the density and dispersion of cigarette butts in the urban environment and to estimate the leakage of pollution from it to the environment. For this purpose, the cigarette butt pollution index was used in 14 locations. Observations were made during a year and once a month for each location. The study of the locations was done with the same conditions on weekend and working days. The amount of heavy metal leakage was estimated based on the average weight of cigarette butts and the ratio of metal leakage in different weather conditions. The results showed that the annual average of index for the studied locations was 1.36 (SD 0.11) to 10.6 (SD 1.23). Based on this, 28.5% of the locations were in the low pollution status and 42.8% were in the significant pollution status and worse. On average, the index on weekend decreased by 32.3 percent in all locations, and the average index of the studied locations in spring and summer was 26.2 percent higher than in autumn and winter. The average leakage of heavy metals including chromium, cadmium, zinc, lead, copper, and nickel from littered cigarette butts in commercial, residential, and recreational areas was estimated to be 0.27, 0.079, and 0.17 µg per square meter, respectively. Cigarette butt is one of the most abundant litter in the studied area, which is the source of many pollutants, including heavy metals. This hazardous waste is a serious threat to the urban environment.

Photocatalytic oxidation of ciprofloxacin by UV/ α-Fe2O3/sulfite: mechanism, kinetic, degradation pathway.

This study was aimed to investigate the synergistic effect of sulfite reducing agent on the UV/hematite (α-Fe2O3) photocatalytic process performance in the removal of ciprofloxacin from the aqueous solutions. For this purpose, influence of the operation parameters including initial antibiotic concentration, pH, sulfite to hematite molar ratio and the reaction time on the UV/hematite/sulfite (UHS) performance was evaluated. UV alone, UV/hematite (α-Fe2O3) (UH) and UV/sulfite (US) processes indicated to have little influence on the ciprofloxacin degradation. The simultaneous presence of hematite and sulfite in the reaction environment was significantly improved the degradation efficiency, as UHS process indicated an increase of 89%, 64% and 59% in the removal performance than that of UV alone, UH and US processes, respectively. Under the selected condition (pH of 7.0 and sulfite/hematite molar ratio of 1:3), 94% of ciprofloxacin (CFX) was degraded after 5 min of reaction. In addition, robs (mg L-1 min) value for UHS process was 25.26, 6 and 4.8 times that of UV alone, UH and US processes, respectively. The EEO and TCS values for UV alone, US, UH and UHS processes were (44.21 kWh/m-3 and 2.08 $ m-3), (10.5 kWh/m-3 and 1.1 $ m-3), (4.8 kWh/m-3 and 1.04 $ m-3) and (1.75 kWh/m-3 and 0.85 $ m-3), respectively. In addition, the study of the reaction mechanism showed hydroxyl and sulfate radicals play a vital role in the degradation of CFX by UHS process.

Clean environment index: A new approach for litter assessment.

Littered waste is one of the ubiquitous problems in urban environments. In this study, urban environmental pollution was evaluated for the first time using a new developed index. The findings indicated that cigarette butts with an average 58% are the largest share in the composition of littered waste. In addition, the numbers of littered wastes throughout the study area had a spatial variation. According to clean environment index (CEI), the entire study area was found to be in a moderate status. However, 40% of the study areas were classified in a dirty and extremely dirty status. Comparison of the studied urban land-uses showed that residential land use with CEI equal to 3.38 is interpreted in the clean status, while commercial land use with CEI equal to 15.05 can be classified in the dirty status. The application of CEI has a good capability to assess littered waste; this index can be employed to evaluate the pollution of urban sidewalks and other environments such as beaches.

Cigarette butts as a super challenge in solid waste management: a review of current knowledge.

Filtered cigarette is the most common type of tobacco used and cigarette butt is the most important environmental consequence of smoking. This study aimed to investigate the cigarette butt management and identify future needs to improve the current situation. The results showed that cigarette butts are the most abundant and widespread hazardous waste in the world. The current form of cigarette butt management has inferior performance that faced waste management systems with serious challenges. The results showed that reducing the littering rate and recycling are known as basic strategies in the management of this hazardous waste. Future studies should focus on reducing cigarette butt pollution and the amount of pollutant leakage from them.

Cigarette butt littering consequences: a study of pollution rate on beaches and urban environments.

Cigarette butts are hazardous wastes that are not properly discarded by most smokers. They are one of the most abundant litters in the environment and a threat to various organisms because they leak numerous pollutants. This study aimed to assess the distribution of cigarette butts in a coastal city south of the Caspian Sea in Mazandaran Province, Iran. Observations were performed using the visual survey technique based on standardized protocol. The results showed 11,261 littered cigarette butts in 15 studied urban areas ( an average of 0.306 units per square meter). Also, the average density of littered cigarette butts on the studied beaches was 0.106 per square meter. The littered cigarette butts had significant spatial variation, and the number of counts was 135 to 2090. The land-use has a significant effect on the density of littered cigarette butts due to its population density. The inquiry's index demonstrated that 33.3% of the studied urban areas are high pollution and severe pollution, while all beaches are high and severe. Therefore, a significant focus must be considered to reduce cigarette butts littering due to the collection problems and challenges of cigarette butt management. Because the pollution on the beaches is higher than in urban areas, improving waste management services and establishing a regular cleaning program are essential.

Estimation of the heavy metals released from cigarette butts to beaches and urban environments.

Cigarette butts (CB) are considered as a commonly littered waste. This hazardous waste contains a variety of pollutants. This study was developed to estimate the release of some heavy metals from CBs to the environment in different climatic conditions in different scenarios. To this end, CBs samples were obtained through artificial smoking from 10 high-consumption brands in the Iranian market, and their samples in urban areas were taken and analyzed in terms of heavy metals pollution. The results showed that the average concentrations of Lead, Cadmium, Chromium, Zinc, Copper, Nickel in the studied CBs were 1.71, 0.36, 1.59, 24.61, 12.83, and 2.66 µg/g, respectively. The long persistency of CBs in the environment leads to increased release of all heavy metals to 9.7%. In addition, the rainfall can accelerate the leaching of heavy metals to 17.7% compared to the control scenario. The total mean concentrations of the studied metals in the CBs samples collected from the urban areas in rainy and non-rainy conditions were measured to be 32.67-51.81 µg/g, respectively. According to the data obtained for the amount of each heavy metal releases in four scenarios, 147.5 kg/year and 57.3 kg/year heavy metals are released to the environment in the worst and the best-case scenarios. This study showed that CBs littering lead to the release of heavy metals into the environment; it is necessary to reduce the density of CBs in urban and public environments by training the smokers as well as increasing the efficiency of the urban cleaning system.