Sorption kinetics of chlortetracyline and tylosin on sandy loam and heavy clay soils.

Antibiotics may appear in the environment when manure, sewage sludge, and other organic amendments are added to soils. There is concern that the presence of antibiotics in soils may lead to the development of antibiotic-resistant bacteria which may spread to the rest of the environment. This paper aims at evaluating the sorption kinetics of two antibiotics frequently used in pig production. The results indicate that sorption of chlortetracycline (CTC) and tylosin (TYL) in sandy loam and clay occurs very fast. More than 95% of the CTC adsorption is completed within 10 min on both soils and of TYL within 3 h. These results suggest that 24-h soil and antibiotic solution mixtures is enough for sorption studies. Also, there is less likelihood that these antibiotics will leach through soil and appear in the ground water since their sorption on soils is very high unless they are carried by soil particles through preferential flow. There was also no effect of soil sterilization on sorption kinetics of these antibiotics thus suggesting that there is minimal probability of the antibiotics degrading by microorganisms during 24- to 48-h adsorption studies.

Gas-phase sorption-desorption of propargyl bromide and 1,3-dichloropropene on plastic materials.

The goal of this research was to provide information for choosing appropriate materials for studying gas-phase concentrations of propargyl bromide (3BP) and 1,3-dichloropropene (1,3-D) in laboratory experiments. Several materials were tested and found to sorb both gas-phase chemicals in the following order: stainless steel (SS) < Teflon polytetrafluoroethylene (PTFE-FEP) approximately flexible polyvinyl chloride (PVC) approximately acrylic < low-density polyethylene (PE) < vinyl approximately silicone < polyurethane foam (PUF). Sorption of SS was insignificant and PUF sorbed all the fumigant that was applied. For the other materials, linear sorption coefficients (Kd) for 3BP ranged from 3.0 cm3 g(-1) for PVC to 215 cm3 g(-1) for silicone. Freundlich sorption coefficients for 1,3-D ranged from 11.5 to 371 cm3 g(-1). First-order desorption rate constants in an open system ranged from 0.05 to 1.38 h(-1) for 3BP and from 0.07 to 1.73 h(-1) for 1,3-D. In a closed system, less than 2% of sorbed fumigant desorbed from vinyl while up to 99% desorbed from PVC within 24 h when equilibrated at the highest headspace concentration. Sorption of both fumigants was linearly related to the square root of time except for vinyl and silicone. This may indicate non-fickian diffusion of fumigant into the polymer matrix. Vinyl, silicone, PE, and PUF should be avoided for quantitative study of organic gases, except possibly as a trapping medium. Use of PTFE, PVC, and acrylic may require correction for sorption-desorption and diffusion.

Role of macropore continuity and tortuosity on solute transport in soils: 2. Interactions with model assumptions for macropore description.

The impact of macropore description on solute transport predictions in soils is not well understood. A 2-D Galerkin finite element model was used to compare different approaches for describing macropore flow in soil. The approaches were: a modification of the hydraulic conductivity function (Hydraulic function), the lumping of all macropores into one single straight macropore (Lumping), the use of an exchange factor between microporosities and macroporosities that occupy the same area (Dual porosity), and a detailed description of each macropore (Full description, base case). Simulated breakthrough curves were obtained with domains that contained one or more macropores of different shapes under both steady state and transient flow conditions. The Hydraulic function approach was not sensitive to macropore continuity and tortuosity. When the macropores were open at the soil surface and the solute was surface applied, the first three approaches underestimated both breakthrough curves and solute distribution in the profile compared to the Full description approach. When the solute was initially incorporated in the soil, the first three approaches overestimated the breakthrough curves compared to the Full description approach. The first three approaches also underestimated the heterogeneity of solute distribution in the profile compared to the Full description approach, mostly when the macropores were tortuous. The differences between predicted breakthrough curves with different approaches decreased with an increase in tortuosity and a decrease in surface continuity. To simplify macropore description, the Dual porosity approach was the better of the first three approaches for predicting breakthrough curves provided the exchange factor between macropores and matrix porosity was available.

Role of macropore continuity and tortuosity on solute transport in soils: 1. Effects of initial and boundary conditions.

Models developed for solute transport vary in their assumptions on macropore continuity and tortuosity. It is unclear how much simplification can be made in computer models to characterize macropore effects on water and solute transport through soils. The objectives of this study were to assess how the importance of macropore continuity and tortuosity varies (1) with various initial and boundary conditions (this paper) and (2) with simplifying model assumptions for macropore description (companion paper). The above assessments were made with a computer model based on 2-D Galerkin finite element solution of Richards' equation for water flow and convective-dispersive equation for solute transport. The model can simultaneously handle macropores of varying length, size, shape, and continuity. Model predictions were in agreement with laboratory data for different macropore shapes and continuities under transient flow conditions. Simulations for various initial and boundary conditions showed that surface connected macropores under ponded conditions and under high intensity rainfalls favored the rapid transport of solutes. However, solute transport was delayed if the solute was initially incorporated in the soil even when macropores were connected to the soil surface. Macropores not connected to the soil surface only slightly accelerated solute transport for any boundary conditions. Macropore tortuosity did not influence breakthrough curves as much as the continuity but greatly influenced solute distribution in the profile. The importance of macropore continuity and tortuosity on preferential transport increased with an increase in solute retardation. General guidelines for simplifying continuity and tortuosity for modeling solute transport are presented for various initial and boundary conditions.

A dynamic two-dimensional system for measuring volatile organic compound volatilization and movement in soils.

There is an important need to develop instrumentation that allows better understanding of atmospheric emission of toxic volatile compounds associated with soil management. For this purpose, chemical movement and distribution in the soil profile should be simultaneously monitored with its volatilization. A two-dimensional rectangular soil column was constructed and a dynamic sequential volatilization flux chamber was attached to the top of the column. The flux chamber was connected through a manifold valve to a gas chromatograph (GC) for real-time concentration measurement. Gas distribution in the soil profile was sampled with gas-tight syringes at selected times and analyzed with a GC. A pressure transducer was connected to a scanivalve to automatically measure the pressure distribution in the gas phase of the soil profile. The system application was demonstrated by packing the column with a sandy loam in a symmetrical bed-furrow system. A 5-h furrow irrigation was started 24 h after the injection of a soil fumigant, propargyl bromide (3-bromo-1-propyne; 3BP). The experience showed the importance of measuring lateral volatilization variability, pressure distribution in the gas phase, chemical distribution between the different phases (liquid, gas, and sorbed), and the effect of irrigation on the volatilization. Gas movement, volatilization, water infiltration, and distribution of degradation product (Br-) were symmetric around the bed within 10%. The system saves labor cost and time. This versatile system can be modified and used to compare management practices, estimate concentration-time indexes for pest control, study chemical movement, degradation, and emissions, and test mathematical models.